1-methyl-cyclohexa-2,4-diene-1,2-dicarboxylic acid | 100523-81-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-methyl-cyclohexa-2,4-diene-1,2-dicarboxylic acid
• 英文别名: 1-Methyl-cyclohexa-2,4-dien-1,2-dicarbonsaeure；1-Methylcyclohexa-2,4-diene-1,2-dicarboxylic acid
• CAS: 100523-81-7
• 化学式: C₉H₁₀O₄
• 分子量: 182.176
• InChiKey: CBERPDNPMKPZAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 水 作用下， 生成 1-methyl-cyclohexa-2,4-diene-1,2-dicarboxylic acid
  参考文献：
  名称：

  Kutscherow et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 793,800; engl. Ausg. S. 781, 786

  摘要：

  DOI：

文献信息

• A powder coating composition
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0365428A2

  公开（公告）日：1990-04-25

  A powder coating composition, which comprises a mixture consisting essentially of (a) a carboxyl terminated polyester resin having at least 2 carboxylic groups per molecule and (b) an alicyclic epoxy resin having ether bonds and up to three kinds of substituents is disclosed. The powder coating composition has excellent properties including excellent smoothness on the surface, resistance to heat, and good outdoor durability of the coated layer formed after curing, in the class of polyester type coatings. Consequently, the powder coating composition can be advantageously used in various fields, such as domestic electric appliances, automobile accessories, furniture, and the like.

  本发明公开了一种粉末涂料组合物，它主要由以下物质的混合物组成：(a) 每分子至少有 2 个羧基的羧基端聚酯树脂；(b) 具有醚键和多达三种取代基的脂环族环氧树脂。 在聚酯类涂料中，该粉末涂料组合物具有优异的性能，包括出色的表面平滑度、耐热性和固化后形成的涂膜层良好的户外耐久性。 因此，该粉末涂料组合物可以很好地应用于各种领域，如家用电器、汽车配件、家具等。
• Compositions, expoxidized compositions, a heat-curable resin composition, an epoxy resin composition, radically polymerized composition, a curable resin composition and a polymer having epoxy groups
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0540027A2

  公开（公告）日：1993-05-05

  Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), are disclosed. (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at least one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group. Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof. The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.

  本发明公开了由具有乙烯基作为侧链的化合物组成的组合物(I)、(II)和(III)及其环氧化组合物(XI)、(XII)和(XIII)，这些组合物可以通过(a)与(b)或(b)+(c)和或(d)的各种反应组合来制备。 (a)是分子中至少具有一个乙烯基和一个环氧基的至少一种化合物；(b)是多基性化合物、其酸酐、末端具有羧基的聚合物和侧链具有羧基的聚合物中的至少一种；(c)是具有至少一个活泼氢原子的至少一种有机化合物；(d)是具有羟基的不饱和单羧基化合物或不饱和单羧基酯中的至少一种。 热固化组合物和环氧树脂组合物由上述组合物、自由基引发剂或固化剂、通过自由基（共）聚合组合物（III）或环氧化组合物（XIII）得到的聚合物组合物组成。 环氧化组合物(XI)和(XII)可以提供具有优异性能（如耐热性、室外耐久性和进一步的电性能）的涂层或成型制品。
• Epoxidised compositions
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0859021A2

  公开（公告）日：1998-08-19

  Compositions(I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions(XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), are disclosed. (a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom. Heat curable compositions and epoxy resin compositions can be made which comprise the above-mentioned compositions and a radical initiator or a curing agent, a polymer composition obtained by radically (co)polymerizing the compositions(III) or the epoxidized compositions(XIII) thereof. The epoxidized compositions(XI) and (XII) can provide a coating layer or a formed article having excellent properties such as heat resistance, outdoor durability and further electric properties.

  本发明公开了由具有乙烯基作为侧链的化合物组成的组合物(I)、(II)和(III)及其环氧化组合物(XI)、(XII)和(XIII)，这些组合物可以通过(a)与(b)或(b)+(c)的各种反应组合制备。 (a)是分子中至少具有一个乙烯基和一个环氧基的化合物；(b)是多碱性化合物、其酸酐、末端具有羧基的聚合物和侧链具有羧基的聚合物中的至少一种；(c)是至少具有一个活泼氢原子的有机化合物。 热固化组合物和环氧树脂组合物可以由上述组合物和自由基引发剂或固化剂、通过自由基（共）聚合组合物（III）或环氧化组合物（XIII）得到的聚合物组合物组成。 环氧化组合物(XI)和(XII)可以提供具有优异性能（如耐热性、室外耐久性和进一步的电性能）的涂层或成型制品。
• US5494977A
  申请人：——

  公开号：US5494977A

  公开（公告）日：1996-02-27
• US5510428A
  申请人：——

  公开号：US5510428A

  公开（公告）日：1996-04-23