| 228269-62-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 228269-62-3
• 化学式: C₃₂H₄₆MnN₂O₂
• 分子量: 545.667
• InChiKey: DAJKSWJQXPPGMD-GLOXORAVSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine 在 lithium chloride 作用下， 以 乙醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Study on Mn(III)‐Salen and Catalysis for Styrene Oxidation

  摘要：

  In this paper, three Mn(III)-Salen complexes are synthesized and their catalytic activity for styrene oxidation were studied. Four Shifft-basa are prepared by condensation of salicylaldehyde or its derivatives with diamine, then chelated with Mn and formed into Mn(III)-Salen complexes. Their chemical structures are characterized by IR, UV, etc. Furthermore, the catalytic activities of the Salen compounds for styrene oxidation with oxygen are primarily explored. The experiments show that among them, Mn(III)-Salen-2 is the most excellent catalyst for styrene oxidation with high conversion of styrene (77.1%) and selectivity of benzaldehyde (90.4%).

  DOI：

  10.1080/15533170802132014