1-Phenyl-Δ²-pyrazolin-carbonsaeure-(3) | 90915-40-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1-Phenyl-Δ²-pyrazolin-carbonsaeure-(3)
• 英文别名: 1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid；2-Phenyl-3,4-dihydropyrazole-5-carboxylic acid
• CAS: 90915-40-5
• 化学式: C₁₀H₁₀N₂O₂
• 分子量: 190.202
• InChiKey: MHAWSHGZLLOJFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52.9
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• Use of phenylpyrazolin-3-carboxylates for improving plant yield
  申请人：BAYER INTELLECTUAL PROPERTY GMBH

  公开号：US10435372B2

  公开（公告）日：2019-10-08

  Compounds (A) can be used for increasing the yield of useful plants or crop plants with respect to their harvested plant organs, wherein the Compound (A) is selected from compounds of the formula (I) or salts thereof, in which (R1)n is n radicals R1 where the R1 are identical or different and are each halogen or (C1-C4)-haloalkyl, n is an integer from 1 to 3, R2 is hydrogen, (C1-C6)-alkyl, (C1-C4)-alkoxy-(C1-C4)-alkyl, (C3-C6)-cycloalkyl, tri-(C1-C4)-alkyl-silyl or tri-(C1-C4)-alkyl-silylmethyl, R3 is hydrogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl or (C3-C6)-cycloalkyl, and R4 is hydrogen or (C1-C12)-alkyl, preferably mefepyr-diethyl (Compound (A1)]

  化合物(A)可用于提高有用植物或作物植物收获植物器官的产量，其中化合物(A)选自式(I)化合物或其盐类、 其中 (R1)n 是 n 个自由基 R1，其中的 R1 相同或不同，且各自为卤素或 (C1-C4)- 卤代烷基、 n 是 1 至 3 的整数、 R2 是氢、(C1-C6)-烷基、(C1-C4)-烷氧基-(C1-C4)-烷基、(C3-C6)-环烷基、三(C1-C4)-烷基-硅基或三(C1-C4)-烷基-硅甲基、 R3 是氢、(C1-C6)-烷基、(C1-C6)-卤代烷基、(C2-C6)-烯基、(C2-C6)-炔基或 (C3-C6)-环烷基，以及 R4 是氢或 (C1-C12)- 烷基、 优选甲epyr-二乙基（化合物 (A1)
• Combinations of herbicidal aromatic carboxylic acids and safeners
  申请人：——

  公开号：US20030232725A1

  公开（公告）日：2003-12-18

  Combinations of herbicidal aromatic carboxylic acids and safeners The invention relates to a herbicide-safener combination, which comprises: (A) one or more herbicidal auxin type of aromatic carboxylic acids or salts thereof, for example dicamba, chloramben or 2,3,6-trichlorobenzoic acid (2,3,6-TBA), and (B) one or more safeners selected from the group consisting of: (B1) active compounds of the heterocyclic carboxylic acid type and their derivatives, preferably their esters or salts, selected from the group consisting of (B1.1) compounds of the phenylpyrazolin-3-carboxylic acid type, (B1.2) derivatives of the phenylpyrazolecarboxylic acid type, (B1.3) compounds of the triazolecarboxylic acid type, (B1.4) compounds of the 5-benzyl-, 5-phenyl- or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type, (B1.5) flurazole and (B1.6) dimepiperate, (B2) active compounds, or salts thereof, which, in addition to a herbicidal action against harmful plants, also have a safener action in crop plants such as rice, selected from the group consising of (B2.1) daimuron (B2.2) cumyluron (B2.3) methoxyphenone and (B2.4) CSB (B3) safening active N-acylsulfonamides selected from the group consisting of (B3.1) N′-acyl-N-benzoyl-aminobenzolsulfonamides or their salts (B3.2) acylsulfamoylbenzamides or salts thereof, with the exception of herbicide-safener combinations comprising dicamba or salts thereof and a safener selected from the group (B1.4) defined above. The invention is also directed to the respective method for protecting crops, the method for weed control using the combination and the use of compounds (B) for safening compounds (A).

  芳香族羧酸除草剂和安全剂的组合物 本发明涉及一种除草剂-安全剂组合物，它包括 (A) 一种或多种除草助剂类型的芳香族羧酸或其盐类，例如麦草畏、氯虫苯甲酰胺或 2,3,6-三氯苯甲酸（2,3,6-TBA），以及 (B) 选自以下组别的一种或多种安全剂： (B1) 杂环羧酸类活性化合物及其衍生物，最好是其酯类或盐类，选自由以下 组别 (B1.1) 苯基吡唑啉-3-羧酸类化合物、 (B1.2) 苯基吡唑-3-羧酸类衍生物、 (B1.3) 三唑羧酸类化合物、 (B1.4) 5-苄基、5-苯基或 5,5-二苯基-2-异噁唑啉-3-羧酸类化合物、 (B1.5) 氟唑和 (B1.6) 二甲戊哌酸、 (B2) 除对有害植物有除草作用外，还对作物（如水稻）有安全作用的活性化合物 或其盐类，选自以下组别 (B2.1) 敌草隆 (B2.2) 久效隆 (B2.3) 甲氧苯丙酮和 (B2.4) CSB (B3) 选自以下组别的具有安全活性的 N-酰基磺酰胺类化合物 (B3.1) N′-酰基-N-苯甲酰基氨基苯磺酰胺或其盐类 (B3.2)酰基磺酰胺基苯甲酰胺或其盐，但除草剂-安全剂组合物除外，该组合物由麦草畏或其盐和选自上文定义的组(B1.4)的安全剂组成。 本发明还涉及保护作物的相应方法、使用组合物控制杂草的方法以及使用化合物（B）使化合物（A）安全化的方法。
• VERFAHREN ZUR HERSTELLUNG VON 1-PHENYLPYRAZOLIN-3-CARBONSÄURE-DERIVATEN
  申请人：Bayer CropScience GmbH

  公开号：EP1012143B1

  公开（公告）日：2003-12-17
• COMBINATIONS OF HERBICIDAL AROMATIC CARBOXYLIC ACIDS AND SAFENERS
  申请人：Bayer CropScience GmbH

  公开号：EP1515606A2

  公开（公告）日：2005-03-23
• SAFENING METHOD
  申请人：Bayer CropScience AG

  公开号：EP1791425A2

  公开（公告）日：2007-06-06