1-bromo-19-methyleicosane | 372988-43-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 1-bromo-19-methyleicosane
• 英文别名: 1-Bromo-19-methylicosane
• CAS: 372988-43-7
• 化学式: C₂₁H₄₃Br
• 分子量: 375.476
• InChiKey: XDCHRSSLALGJGS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  22
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-bromo-19-methyleicosane 在 盐酸 、 硫酸 、 sodium ethanolate 、 sodium nitrite 作用下， 以 1,4-二氧六环 、 乙醇 为溶剂， 反应 23.5h， 生成 (+/-)-2-hydroxy-21-methyldocosanoic acid
  参考文献：
  名称：

  Sex Pheromones of the Hair Crab Erimacrus isenbeckii. II. Synthesis of Ceramides

  摘要：

  To confirm their structures and to assess the pheromonal activity, novel ceramides, possible sex pheromones of the hair crab Erimacrus isenbeckii, were synthesized from D-galactose. The synthetic ceramides were identical with the natural ceramides.

  DOI：

  10.1021/np010177m
• 作为产物：
  描述：

  12-bromo-2-methyl-3(E/Z)-dodecene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 69.5h， 生成 1-bromo-19-methyleicosane
  参考文献：
  名称：

  Sex Pheromones of the Hair Crab Erimacrus isenbeckii. II. Synthesis of Ceramides

  摘要：

  To confirm their structures and to assess the pheromonal activity, novel ceramides, possible sex pheromones of the hair crab Erimacrus isenbeckii, were synthesized from D-galactose. The synthetic ceramides were identical with the natural ceramides.

  DOI：

  10.1021/np010177m

文献信息

• Sex Pheromones of the Hair Crab <i>Erimacrus </i><i>i</i><i>senbeckii</i>. II. Synthesis of Ceramides
  作者：Naoki Asai、Nobuhiro Fusetani、Shigeki Matsunaga

  DOI：10.1021/np010177m

  日期：2001.9.1

  To confirm their structures and to assess the pheromonal activity, novel ceramides, possible sex pheromones of the hair crab Erimacrus isenbeckii, were synthesized from D-galactose. The synthetic ceramides were identical with the natural ceramides.