4-乙烯基苄基苯基硫醚 | 49858-45-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-乙烯基苄基苯基硫醚
• 英文名称: 4-vinylbenzyl phenyl sulfide
• 英文别名: phenyl(4-vinylbenzyl)sulfane；1-ethenyl-4-(phenylsulfanylmethyl)benzene
• CAS: 49858-45-9
• 化学式: C₁₅H₁₄S
• 分子量: 226.342
• InChiKey: NQQISFXOWMYTAM-UHFFFAOYSA-N

物化性质

• 熔点：
  81-82 °C(Solv: ethanol (64-17-5))
• 沸点：
  356.2±21.0 °C(Predicted)
• 密度：
  1.08±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  p-(2-phenylthio-1-chloroethyl)benzyltrimethylstannane 以21%的产率得到
  参考文献：
  名称：

  KUTYREV G. A.; KAPURA A. A.; SADYKOVA L. A.; NIKANOROV V. A.; CHERKASOV R+, ZH. OBSHCH. XIMII, 57,(1987) N 1, 56-63

  摘要：

  DOI：

文献信息

• Eco-compatible three component strategies for C-S bond formation in thioether and S-aryl-carbamodithioate compounds catalyzed by copper(II) nanoparticles supported on modified AlPO₄
  作者：Hashem Sharghi、Iman Ghaderi、Mohammad Mahdi Doroodmand

  DOI：10.1002/aoc.3869

  日期：2017.12

  One‐pot and three components C‐S bond formation reactions in thioethers and S‐aryl‐carbamodithioates have been catalyzed by a copper heterogeneous nano‐catalyst supported on modified AlPO4 under different reaction conditions. The above‐mentioned nano‐catalyst has been characterized by various techniques such as SEM, TEM, AFM, XRD, FT‐IR, UV–Vis, CV, BET, TGA, ICP and XPS spectrometry and its particle

  在不同的反应条件下，负载在改性AlPO 4上的铜多相纳米催化剂已经催化了硫醚和S-芳基-氨基甲二硫代酸酯中的一锅和三组分C-S键形成反应。上述纳米催化剂已通过多种技术进行了表征，例如SEM，TEM，AFM，XRD，FT-IR，UV-Vis，CV，BET，TGA，ICP和XPS光谱法，其粒径估计在60–110 nm。最后，在没有任何明显浸出的情况下，催化剂可重复使用多达十个循环是催化剂的杰出性能之一。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• POLYMERIZABLE COMPOSITION, OPTICAL MATERIAL COMPRISING THE COMPOSITION AND METHOD FOR PRODUCING THE MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1524289A1

  公开（公告）日：2005-04-20

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98 % or more. A reduction in a chlorine content of the sulfur compound described above to 0.1 % by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100°C for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化包含分子中至少含有一种表硫化物的化合物的可聚合组合物而获得的固化物，可通过向包含分子中至少含有一种表硫化物的化合物的可聚合组合物中添加香料来减少气味。 将硫的纯度提高到 98% 或更高，可消除镜片的浑浊度。 将上述硫化合物的氯含量降低到 0.1%（重量百分比）或更低，可提高高折射率光学材料的抗氧化性和耐光性，并改善其色调。 在 0.001 至 50 托的减压条件下，将组合物预先在 0 至 100°C 的温度下进行 1 分钟至 24 小时的脱气处理，可获得具有高折射率和高透明度的光学产品。
• ——
  作者：A. S. Dneprovskii、I. V. Fedosov

  DOI：10.1023/a:1013456112725

  日期：——

  4-Vinylbenzyl phenyl ether, 4-phenylbenzyl phenyl ether, 1- and 2-naphtllylmethyl phenyl ethers react with sodium thiophenolate under photochemical stimulation with replacement of the phenoxy group. The composition of reaction products and relation of reactivity to the structure of substrates is consistent with anion-radical mechanism. The corresponding methoxy and cyano derivatives do not undergo the reaction.
• Dneprovskii; Tuchkin, Russian Journal of Organic Chemistry, 1997, vol. 33, # 11, p. 1608 - 1612
  作者：Dneprovskii、Tuchkin

  DOI：——

  日期：——