5,5'-dibromo-2,2'-bipyridine-3,3'-dicarboxylic acid | 1426680-19-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 5,5'-dibromo-2,2'-bipyridine-3,3'-dicarboxylic acid
• 英文别名: 5-Bromo-2-(5-bromo-3-carboxypyridin-2-yl)pyridine-3-carboxylic acid
• CAS: 1426680-19-4
• 化学式: C₁₂H₆Br₂N₂O₄
• 分子量: 401.999
• InChiKey: IZUPUBNQPREOFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,5'-dibromo-2,2'-bipyridine-3,3'-dicarboxylic acid 在 四(三苯基膦)钯 、 氯化亚砜 作用下， 以 甲苯 为溶剂， 生成 diethyl 5,5'-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2,2'-bipyridine-3,3'-dicarboxylate
  参考文献：
  名称：

  RETRACTED: Novel donor–acceptor type thiophene pyridine conjugates: synthesis and ion recognition features

  摘要：

  In order to reveal the effect of the donor units on the structure-property relationship, three novel directly linked donor-acceptor type systems, 1-3, which are based on thiophene and pyridine conjugates, are designed, synthesized and characterized by spectroscopic methods. It is noteworthy that these D-A systems exhibit distinct electrochemical and optical features depending on the strength of the D-unit or the conjugation length. Furthermore, it is found that two of these novel systems, 2 and 3, can be used in both chromogenic and fluorogenic detection of Cu2+ among other ions. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.03.008
• 作为产物：
  描述：

  3,8-二溴菲罗啉 在 potassium permanganate 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 6.0h， 以70%的产率得到5,5'-dibromo-2,2'-bipyridine-3,3'-dicarboxylic acid
  参考文献：
  名称：

  RETRACTED: Novel donor–acceptor type thiophene pyridine conjugates: synthesis and ion recognition features

  摘要：

  In order to reveal the effect of the donor units on the structure-property relationship, three novel directly linked donor-acceptor type systems, 1-3, which are based on thiophene and pyridine conjugates, are designed, synthesized and characterized by spectroscopic methods. It is noteworthy that these D-A systems exhibit distinct electrochemical and optical features depending on the strength of the D-unit or the conjugation length. Furthermore, it is found that two of these novel systems, 2 and 3, can be used in both chromogenic and fluorogenic detection of Cu2+ among other ions. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.03.008