trimethyl(6-phenylhexa-2,3-dienyl)silane | 184577-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trimethyl(6-phenylhexa-2,3-dienyl)silane
• CAS: 184577-76-2
• 化学式: C₁₅H₂₂Si
• 分子量: 230.425
• InChiKey: TXNZIPXLBIJNCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.67
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trimethyl(6-phenylhexa-2,3-dienyl)silane 在 碳酸氢钠 、 Selectfluor 作用下， 以 丙酮 为溶剂， 生成 [(E)-3-fluorohexa-3,5-dienyl]benzene 、 [(Z)-3-fluorohexa-3,5-dienyl]benzene
  参考文献：
  名称：

  Electrophilic Fluorodesilylation of Allenylmethylsilanes:  A Novel Entry to 2-Fluoro-1,3-dienes

  摘要：

  Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds.

  DOI：

  10.1021/ol047319z
• 作为产物：
  描述：

  5-phenylpent-1-yn-3-ol 在 三乙胺 、 lithium chloride 作用下， 以 四氢呋喃 、 乙醚 、 二氯甲烷 为溶剂， 反应 5.5h， 生成 trimethyl(6-phenylhexa-2,3-dienyl)silane
  参考文献：
  名称：

  Electrophilic Fluorodesilylation of Allenylmethylsilanes:  A Novel Entry to 2-Fluoro-1,3-dienes

  摘要：

  Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds.

  DOI：

  10.1021/ol047319z

文献信息

• Electrophilic Fluorodesilylation of Allenylmethylsilanes:  A Novel Entry to 2-Fluoro-1,3-dienes
  作者：M Carmen Pacheco、Véronique Gouverneur

  DOI：10.1021/ol047319z

  日期：2005.3.1

  Various fluorodienes were prepared by treatment of the corresponding allenylmethylsilanes with Selectfluor. This is the first route to these compounds not based on the use of a fluorinated building block. The reaction allows the preparation of 2-fluoro-1,3-dienes with several substitution patterns, including di- and trisubstituted compounds.