[Cu(HOIP)(1,4-bdc)] | 1189184-21-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [Cu(HOIP)(1,4-bdc)]
• 英文别名: [Cu(2-(4-hydroxylbenzene) imidazo[4,5-f]1,10-phenanthroline)(1,4-benzenedicarboxylate)]
• CAS: 1189184-21-1
• 化学式: C₈H₄O₄*C₁₉H₁₂N₄O*Cu
• 分子量: 539.994
• InChiKey: WDUNVZBTMJWFQX-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2-(4-hydroxyphenyl)imidazo[4,5-f][1,10]phenanthroline 、 copper(II) choride dihydrate 、 对苯二甲酸 在 NaOH 作用下， 以 甲醇 、 水 为溶剂， 以11%的产率得到[Cu(HOIP)(1,4-bdc)]
  参考文献：
  名称：

  Extended structures of three new coordination polymers based on 1,10-phenanthroline derivatives and 1,4-benzenedicarboxylate mixed ligands: Preparation, structural characterization and properties

  摘要：

  Three coordination polymers, namely, [Cd(HOIP)(2)(1,4-bdc)] (1), [Cu(HOIP)(1,4-bdc)] (2) and [Cu(PDIP)-(1,4-bdc)] (3) (HOIP = 2-(4-hydroxylbenzene) imidazo[4,5-f] 1,10-phenanthroline, PDIP = 2-(3-pyridine) imidazo[4,5-f] 1,10-phenanthroline, and 1,4-bdc = 1,4-benzenedicarboxylate), have been synthesized under the hydrothermal conditions. All complexes have been characterized by elemental analyses, IR and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 possesses infinite one-dimensional (1D) chain bridged by 1,4-bdc ligands, complexes 2 and 3 both exhibit two-dimensional (2D) (4,4) network structures based on dinuclear [Cu2O2] units. However, the weak interactions are different in complexes 1-3. Moreover, the thermal properties of all complexes, fluorescence property of 1, and the electrochemical behavior of 3 are also reported in this paper. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.11.038