CFA6 | 1799-55-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: CFA6
• 英文别名: Acrylic acid 2-(pentadecafluoroheptyl)ethyl ester；3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-pentadecafluorononyl prop-2-enoate
• CAS: 1799-55-9
• 化学式: C₁₂H₇F₁₅O₂
• 分子量: 468.162
• InChiKey: PKPKRTXQJZSNCQ-UHFFFAOYSA-N

物化性质

• 沸点：
  49-52 °C(Press: 1 Torr)
• 密度：
  1.523±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  N-pivaloyl indole 、 CFA6 在 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 sodium acetate 作用下， 以57 %的产率得到
  参考文献：
  名称：

  铑催化电化学 C7-吲哚烯基化

  摘要：

  铑催化和电化学合成的结合使得吲哚的 C7−H 电烯基化成为可能。

  DOI：

  10.1002/ijch.202300103
• 作为产物：
  描述：

  1H,1H,2H,2H-pentadecafluoro-nonan-1-ol 、 丙烯酸 生成 CFA6
  参考文献：
  名称：

  MARUYAMA, TOSIKI;JOKOO, XIDEHDZIRO

  摘要：

  DOI：

文献信息

• COMPOSITE MATERIAL HAVING ANTIFOULING PROPERTY
  申请人：NBC inc.

  公开号：EP1972437A1

  公开（公告）日：2008-09-24

  [Object] To provide a dustproof, antifouling, and highly durable composite material. [Solving Means] An inorganic fine particle layer containing inorganic fine particles and a binder component is formed on a surface of a substrate by chemical bonding. The inorganic fine particles are coated with silane monomer each having an unsaturated bond. The content of the binder component is in the range of 0.1% by mass to 40% by mass to the content of the inorganic fine particles.

  [目的]提供一种防尘、防污和高度耐用的复合材料。 [解决方法] 通过化学键合在基材表面形成含有无机细颗粒和粘合剂成分的无机细颗粒层。无机细颗粒上涂有硅烷单体，每种单体都有一个不饱和键。粘合剂成分的含量为无机微粒含量的 0.1% 至 40%。
• RESIN COMPOSITION
  申请人：Asahi Kasei E-materials Corporation

  公开号：EP2246377A1

  公开（公告）日：2010-11-03

  The present invention provides a resin composition containing a resin (a1) containing a siloxane bond and having a number-average molecular weight of 500 or more and 300,000 or less, and a resin (a2) containing no siloxane bond and having a number-average molecular weight of 1,000 or more and 300,000 or less.

  本发明提供了一种树脂组合物，其中包含一种含有硅氧烷键且数均分子量在 500 或以上、300,000 或以下的树脂（a1），以及一种不含硅氧烷键且数均分子量在 1,000 或以上、300,000 或以下的树脂（a2）。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。
• Fluororesin-laminated acrylic resin film
  申请人：KANEKA CORPORATION

  公开号：EP2325005A2

  公开（公告）日：2011-05-25

  An object of the present invention is to provide a novel multilayer film that can be employed also for use in interior and exterior members of vehicles, and that has excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin-laminated acrylic resin film, wherein a fluororesin film layer comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和抗污性，例如抗乳酸和抗防晒性。本发明涉及一种氟树脂层压丙烯酸树脂薄膜，其中，在由丙烯酸树脂（A）组成的薄膜层的至少一个面上，层压了由含有含氟烷基（甲基）丙烯酸酯聚合物成分的氟化（甲基）丙烯酸树脂（B）组成的氟树脂薄膜层。
• FLUORINE-CONTAINING (METH)ACRYLIC (CO)POLYMER AND MOLDED BODY FILMS THEREOF
  申请人：Kaneka Corporation

  公开号：EP2537869A1

  公开（公告）日：2012-12-26

  Provided are a fluorine-containing (meth)acrylic (co)polymer that scarcely generates gas when subjected to molding process, and is capable of supplying a molded body excellent in external appearance and transparency; a fluorine-containing (meth)acrylic resin film thereof; and a fluororesin laminated resin film having the same properties. The (co)polymer is a fluorine-containing (meth)acrylic (co)polymer obtained by polymerizing a monomer component including 100 to 70% by weight of a fluoroalkyl (meth)acrylate monomer, and 0 to 30% by weight of a different monomer copolymerizable therewith by effect of a radical polymerization initiator having a solubility in water of 0.1% or less by weight at 25°C, and having 8 to 14 carbon atoms.

  本发明提供了一种含氟（甲基）丙烯酸（共）聚合物，该聚合物在进行成型加工时几乎不产生气体，并且能够提供外观和透明度极佳的成型体；一种含氟（甲基）丙烯酸树脂薄膜；以及一种具有相同性能的氟树脂层压薄膜。该（共）聚合物是一种含氟（甲基）丙烯酸（共）聚合物，通过聚合单体组分获得，该单体组分包括 100 至 70% （重量百分比）的氟烷基（甲基）丙烯酸酯单体和 0 至 30% （重量百分比）的可与之共聚的不同单体，这些单体通过自由基聚合引发剂作用而聚合，自由基聚合引发剂在 25°C 时的水溶解度为 0.1% 或以下（重量百分比），且具有 8 至 14 个碳原子。