2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)-2H-pyrazole-3-carboxamide | 1422677-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)-2H-pyrazole-3-carboxamide
• 英文别名: 2-(3-chloro-2-pyridyl)-N-[-2,4-dichloro6-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)pyrazole-3-carboxamide；2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)pyrazole-3-carboxamide；N-[4,6-dichloro-2-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide；N-[4,6-dichloro-2-[(diethyl-λ-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide；N-[4,6-dichloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide；N-[4,6-dichloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide；2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(diethyl-lambda4-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)pyrazole-3-carboxamide；2-(3-chloropyridin-2-yl)-N-[2,4-dichloro-6-[(diethyl-λ4-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)pyrazole-3-carboxamide
• CAS: 1422677-85-7
• 化学式: C₂₁H₁₇Cl₃F₃N₅O₂S
• 分子量: 566.818
• InChiKey: HRUHMMAFOLUCDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  108
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  3,5-二氯靛红酸酐 在 potassium carbonate 、 三乙胺 作用下， 以 二甲基亚砜 、 乙腈 为溶剂， 反应 8.5h， 生成 2-(3-chloro-2-pyridyl)-N-[2,4-dichloro-6-[(diethyl-λ⁴-sulfanylidene)carbamoyl]phenyl]-5-(trifluoromethyl)-2H-pyrazole-3-carboxamide
  参考文献：
  名称：

  [EN] N-THIO-ANTHRANILAMIDE COMPOUNDS AND THEIR USE AS PESTICIDES
  [FR] COMPOSÉS N-THIO-ANTHRANILAMIDES ET LEUR UTILISATION COMME PESTICIDES

  摘要：

  本发明涉及公式（I）的N-硫代苯甲酰胺化合物，其立体异构体，盐，互变异构体和N-氧化物，其中R1是卤素或卤代甲基；R2是氢，卤素或氰基；R3是氢，C1-C4烷基，C1-C4卤代烷基，C2-C6-烯基或类似物；R4是卤素；R5和R6彼此独立地是可选择取代的C1-C6烷基，C3-C6环烷基，C2-C6烯基，C2-C6炔基，苯基，或者一起代表一个（杂）脂肪链，或类似物；k为0或1。本发明还涉及用于对抗或控制无脊椎动物害虫的方法，用于保护植物繁殖材料和/或由此生长的植物的方法，包括至少一种根据本发明的化合物的植物繁殖材料，用于治疗或保护动物免受寄生虫侵扰或感染的方法，用于制备用于治疗受感染动物和/或保护动物免受寄生虫侵扰或感染的组合物的方法，以及用于作为药物的本发明的化合物。

  公开号：

  WO2013024009A1

文献信息

• [EN] PROCESS FOR PREPARING N-SUBSTITUTED 1H-PYRAZOLE-5-CARBONYLCHLORIDE COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS 1H-PYRAZOLE-5-CARBONYLCHORURES N-SUBSTITUÉS
  申请人：BASF SE

  公开号：WO2013024007A1

  公开（公告）日：2013-02-21

  The present invention relates to a process for preparing an N-substi- tuted 1 H-pyrazole-5-carbonylchloride compound of the formula (I) comprising the steps of i) deprotonating a compound of the formula (II) with a base selected from lithium-organic base having a carbon or nitrogen bound lithium or with a magnesium-organic base having a carbon bound magnesium; and ii) subjecting the product obtained in step (i) to a chlorocarbonylation by reacting it with a reagent selected from the group consisting of phosgene or a phosgene equivalent, to obtain a compound of formula (I).

  本发明涉及一种制备式(I)N-取代1H-吡唑-5-羰基氯化物的过程，包括以下步骤：i) 用选择自碳或氮与锂结合的有机锂碱或碳与镁结合的有机镁碱的碱去质子化式(II)化合物；和ii) 将步骤(i)中获得的产物经氯羰基化反应，与磷酰氯或磷酰氯等效物中选择的试剂反应，以获得式(I)化合物。
• [EN] USE OF SUBSTITUTED OXADIAZOLES FOR COMBATING PHYTOPATHOGENIC FUNGI<br/>[FR] UTILISATION D'OXADIAZOLES SUBSTITUÉS POUR COMBATTRE DES CHAMPIGNONS PHYTOPATHOGÈNES
  申请人：BASF SE

  公开号：WO2017076739A1

  公开（公告）日：2017-05-11

  The present invention relates to novel oxadiazoles of the formula I, or the N-oxides and/or their agriculturally useful salts and to their use for controlling phytopathogenic fungi, or to a method for combating phytopathogenic harmful fungi, which process comprises treating the fungi or the materials, plants, the soil or seeds to be protected against fungal attack, with an effective amount of at least one compound of the formula I, or an N-oxide, or an agriculturally acceptable salt thereof; the present invention also relates to mixtures comprising at least one such compound of the formula I and at least one further pesticidally active substance selected from the group consisting of herbicides, safeners, fungicides, insecticides, and plant growth regulators; and to agrochemical compositions comprising at least one such compound of the formula I and to agrochemical compositions further comprising seeds. Formula (I).

  本发明涉及式I的新型噁二唑化合物，或其N-氧化物和/或其在农业上有用的盐，以及它们用于控制植物病原真菌，或用于对抗植物病原有害真菌的方法，该方法包括用式I的至少一种化合物、N-氧化物或其农业上可接受的盐的有效量处理真菌或需要受到保护免受真菌侵害的材料、植物、土壤或种子；本发明还涉及包含至少一种式I的化合物和从除草剂、安全剂、杀菌剂、杀虫剂和植物生长调节剂组成的至少一种进一步具有杀虫活性的物质的混合物；以及包含至少一种式I的化合物的农药组合物，以及进一步包含种子的农药组合物。Formula (I).
• [EN] ANILINE TYPE COMPOUNDS<br/>[FR] COMPOSÉS DE TYPE ANILINES
  申请人：BASF SE

  公开号：WO2013024008A1

  公开（公告）日：2013-02-21

  The present invention relates to compounds of the formula (I) wherein R1 and R2 independently of one another are hydrogen, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, C3-C10-halocycloalkyl, C2-C10-alkenyl, C2-C10-haloalkenyl or together represent an aliphatic chain, or the like; R3 is halogen, cyano, C1-C8-alkyl, C1-C8- haloalkyl, C3-C8-cycloalkyl, C3-C8-halocycloalkyl, C2-C8-alkenyl, C2-C8-haloalkenyl, C1-C8-alkoxy, phenyl, or the like; R4 is hydrogen, C1-C10-alkyl, C1-C10-haloalkyl, C3-C8- cycloalkyl, C3-C8-halocycloalkyl, C2-C10-alkenyl, C2-C10-haloalkenyl, phenyl, or the like; t is 0 or 1; p is 0, 1, 2, 3 or 4. The present invention also relates to a process for preparing a compound of the formula (I) which comprises reacting a compound of the formula (II) with a compound of the formulae (III) or (IV): where t, p, R1 R3, R3 and R4 are as defined in any of claims 1 to 6 and where A- is an equivalent of an anion having a pΚB of at least 10 (determined under standard conditions in water).

  本发明涉及以下式(I)的化合物，其中R1和R2彼此独立地为氢、C1-C10-烷基、C1-C10-卤代烷基、C3-C10-环烷基、C3-C10-卤代环烷基、C2-C10-烯基、C2-C10-卤代烯基或者一起代表一个脂肪链等；R3为卤素、氰基、C1-C8-烷基、C1-C8-卤代烷基、C3-C8-环烷基、C3-C8-卤代环烷基、C2-C8-烯基、C2-C8-卤代烯基、C1-C8-烷氧基、苯基等；R4为氢、C1-C10-烷基、C1-C10-卤代烷基、C3-C8-环烷基、C3-C8-卤代环烷基、C2-C10-烯基、C2-C10-卤代烯基、苯基等；t为0或1；p为0、1、2、3或4。本发明还涉及一种制备上述式(I)化合物的方法，包括将式(II)的化合物与式(III)或(IV)的化合物反应：其中t、p、R1、R3、R3和R4如权利要求1至6中的任一所定义，A-是至少在水中标准条件下具有至少10的pΚB值的阴离子的当量。
• [EN] PESTICIDAL COMPOUNDS<br/>[FR] COMPOSÉS PESTICIDES
  申请人：BASF SE

  公开号：WO2020109039A1

  公开（公告）日：2020-06-04

  The present invention relates to the compounds of formula (I), and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein the variables are defined according to the description formula (I). The compounds of formula (I), as well as the N-oxides, stereoisomers, tautomers andagriculturally or veterinarily acceptable salts thereof, are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及式(I)的化合物，以及其N-氧化物、立体异构体、互变异构体和农业或兽医学上可接受的盐，其中变量根据描述式(I)中的定义。式(I)的化合物，以及其N-氧化物、立体异构体、互变异构体和农业或兽医学上可接受的盐，对于对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫是有用的。本发明还涉及一种利用这些化合物控制无脊椎动物害虫的方法，以及包括所述化合物的植物繁殖材料和农业和兽医组合物。
• [EN] N-(THIO)ACYLIMINO COMPOUNDS<br/>[FR] COMPOSÉS N-(THIO)ACYLIMINO
  申请人：BASF SE

  公开号：WO2016198613A1

  公开（公告）日：2016-12-15

  The present invention relates to N-(thio)acylimino compoundsof formula (I) wherein the variables are as defined in the claims and the description, and the stereoisomers, tautomers and salts thereof. The invention further relates to agricultural or veterinary compositions comprising such compounds, to the use of the compounds for combating invertebrate pests, and to methods of combating invertebrate pests, which comprises applying such compounds.

  本发明涉及公式（I）中变量如索引和描述中所定义的N-(硫)酰亚胺化合物，以及其立体异构体、互变异构体和盐。该发明还涉及包含这些化合物的农业或兽医组合物，以及利用这些化合物来对抗无脊椎动物害虫的用途，以及施用这些化合物的对抗无脊椎动物害虫的方法。