7-(Diethylamino)-3-[(7-hydroxy-2-oxochromen-3-yl)iminomethyl]chromen-2-one | 1369403-84-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: 7-(Diethylamino)-3-[(7-hydroxy-2-oxochromen-3-yl)iminomethyl]chromen-2-one
• 英文别名: 7-(diethylamino)-3-[(7-hydroxy-2-oxochromen-3-yl)iminomethyl]chromen-2-one
• CAS: 1369403-84-8
• 化学式: C₂₃H₂₀N₂O₅
• 分子量: 404.422
• InChiKey: HSYHWUGUHJXSSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  88.4
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  N-(7-hydroxy-2-oxo-2H-chromen-3-yl)acetamide 在 盐酸 作用下， 以 乙醇 为溶剂， 反应 6.0h， 生成 7-(Diethylamino)-3-[(7-hydroxy-2-oxochromen-3-yl)iminomethyl]chromen-2-one
  参考文献：
  名称：

  A novel coumarin Schiff-base as a Ni(II) ion colorimetric sensor

  摘要：

  A novel coumarin Schiff base compound (1) prepared from 7-diethylaminocoumarin-3-aldehyde and 3-amino-7-hydroxycoumarin was synthesized and evaluated as a chemoselective Ni2+ sensor. Addition of Ni2+ to CH3CN solution of L resulted in a rapid color change from yellow to red together with a large red shift from 465 to 516 nm. Moreover, other common alkali-, alkaline earth-, transition- and rare earth metal ions induced no or minimal spectral changes. Experimental results indicated that L could be used as a potential Ni2+ colorimetric and naked-eye chemosensor in CH3CN solution. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2012.01.017

文献信息

• A novel coumarin Schiff-base as a Ni(II) ion colorimetric sensor
  作者：Lingyun Wang、Decheng Ye、Derong Cao

  DOI：10.1016/j.saa.2012.01.017

  日期：2012.5

  A novel coumarin Schiff base compound (1) prepared from 7-diethylaminocoumarin-3-aldehyde and 3-amino-7-hydroxycoumarin was synthesized and evaluated as a chemoselective Ni2+ sensor. Addition of Ni2+ to CH3CN solution of L resulted in a rapid color change from yellow to red together with a large red shift from 465 to 516 nm. Moreover, other common alkali-, alkaline earth-, transition- and rare earth metal ions induced no or minimal spectral changes. Experimental results indicated that L could be used as a potential Ni2+ colorimetric and naked-eye chemosensor in CH3CN solution. (C) 2012 Elsevier B.V. All rights reserved.