[CuBr2(1,3-bis(1-methylbenzimidazol-2-yl)benzene)(H2O)] | 850309-95-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [CuBr2(1,3-bis(1-methylbenzimidazol-2-yl)benzene)(H2O)]
• 英文别名: dibromocopper;1-methyl-2-[3-(1-methylbenzimidazol-2-yl)phenyl]benzimidazole;hydrate
• CAS: 850309-95-4
• 化学式: C₂₂H₂₀Br₂CuN₄O
• 分子量: 579.781
• InChiKey: ZNLKWFRMGBUOSD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [CuBr2(1,3-bis(1-methylbenzimidazol-2-yl)benzene)(H2O)] 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Synthesis and Properties of Mononuclear and Binuclear Copper(II) Complexes Stabilized bybis‐Benzimidazolyl Ligands

  摘要：

  The reactions of copper(II) halides with 1,3-bis(benzimidazol-2-yl)benzene and its N-methylated derivative afforded binuclear and mononuclear complexes respectively. Mononuclear perchlorate complexes have also been synthesized by the reactions of the aforesaid ligands with hydrated copper perchlorate. The complexes have been characterized by elemental analyses, conductivity and magnetic measurements, TGA studies, IR, electronic, and ESR spectral studies.

  DOI：

  10.1081/sim-200030171
• 作为产物：
  描述：

  1-甲基-2-[3-(1-甲基苯并咪唑-2-基)苯基]苯并咪唑 、 copper(ll) bromide 以 乙醇 为溶剂， 以56%的产率得到[CuBr2(1,3-bis(1-methylbenzimidazol-2-yl)benzene)(H2O)]
  参考文献：
  名称：

  Synthesis and Properties of Mononuclear and Binuclear Copper(II) Complexes Stabilized bybis‐Benzimidazolyl Ligands

  摘要：

  The reactions of copper(II) halides with 1,3-bis(benzimidazol-2-yl)benzene and its N-methylated derivative afforded binuclear and mononuclear complexes respectively. Mononuclear perchlorate complexes have also been synthesized by the reactions of the aforesaid ligands with hydrated copper perchlorate. The complexes have been characterized by elemental analyses, conductivity and magnetic measurements, TGA studies, IR, electronic, and ESR spectral studies.

  DOI：

  10.1081/sim-200030171