1,2,4-Tris-n-butoxybenzol | 41827-30-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,2,4-Tris-n-butoxybenzol
• 英文别名: 1,2,4-Tributoxybenzene
• CAS: 41827-30-9
• 化学式: C₁₈H₃₀O₃
• 分子量: 294.434
• InChiKey: MYQRWQLNVGUQNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,2,4-Tris-n-butoxybenzol 、 丁二酸单甲酯酰氯 生成 3-(2',4',5'-tri-n-butoxybenzoyl)-propionic acid
  参考文献：
  名称：

  Murata; Satoh; Nohara, European Journal of Medicinal Chemistry, 1977, vol. 12, # 1, p. 17 - 20

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2,4-苯三酚 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1,2,4-Tris-n-butoxybenzol
  参考文献：
  名称：

  Murata; Satoh; Nohara, European Journal of Medicinal Chemistry, 1977, vol. 12, # 1, p. 17 - 20

  摘要：

  DOI：

文献信息

• Process for preparation of alkoxybenzamides and thiazolyl isocyanates
  申请人：Awano Hirokazu

  公开号：US20050143581A1

  公开（公告）日：2005-06-30

  An alkoxybenzamide represented by the general formula (3): (wherein R1, R2, R3, R4, and R5 independently indicate a hydrogen atom, an alkyl group having one to six carbon atoms, or an alkoxy group having one to six carbon atoms; if R3 indicates a hydrogen atom or an alkyl group having one to six carbon atoms, R1 indicates an alkoxy group having one to six carbon atoms and R4 indicates an alkyl or alkoxy group having one to six carbon atoms; two adjacent substituents may be coupled with a cross-linking group to form a ring; R6 indicates a heteroaromatic ring; and A indicates an oxygen atom or a sulfur atom) is produced by reacting an alkoxybenzene represented by the general formula (1): (wherein R1, R2, R3, R4, and R5 are defined above) with an isocyanate represented by the general formula (2): (wherein R6 and A are defined above; and n indicates 1 or 2) in the presence of a Lewis acid. Among isocyanates represented by the general formula (2) is a thiazolyl isocyanate represented by the general formula (5): (wherein R1 indicates a hydrogen atom, a saturated or unsaturated alkyl group having one to six carbon atoms, a haloalkyl group having one to six carbon atoms, an alkoxy group having one to six carbon atoms, an alkoxycarbonyl group, or an acyl group; R2 indicates a hydrogen atom, a halogen atom, a saturated or unsaturated alkyl group having one to six carbon atoms, a haloalkyl group having one to six carbon atoms, an alkoxycarbonyl group having one to six carbon atoms, an acyl group, or a substituted or unsubstituted phenyl group; both R1 and R2 do not indicate a hydrogen atom; and n indicates 1 or 2). This thiazolyl isocyanate is produced from two precursors: an aminothiazole and a carbonyl halide. The present invention can provide a method for producing a high yield of alkoxybenzamide with fewer steps, and can also provide thiazolyl isocyanates, which are useful in the production of ureas, carbamates, and aromatic amides having a thiazole ring.

  通式（3）表示的烷氧基苯甲酰胺：（其中R1、R2、R3、R4和R5独立地表示氢原子、具有1至6个碳原子的烷基或具有1至6个碳原子的烷氧基；如果R3表示氢原子或具有1至6个碳原子的烷基，则R1表示具有1至6个碳原子的烷氧基，R4表示具有1至6个碳原子的烷基或烷氧基；两个相邻的取代基可以与交联基耦合形成环；R6表示杂环芳烃环；A表示氧原子或硫原子），通过在路易斯酸的存在下将通式（1）表示的烷氧基苯与通式（2）表示的异氰酸酯反应而制得：（其中R1、R2、R3、R4、R5、R6和A的定义如上；n表示1或2）。通式（2）表示的异氰酸酯中包括通式（5）表示的噻唑基异氰酸酯：（其中R1表示氢原子、具有1至6个碳原子的饱和或不饱和烷基、具有1至6个碳原子的卤代烷基、具有1至6个碳原子的烷氧基、烷氧羰基、或酰基；R2表示氢原子、卤素原子、具有1至6个碳原子的饱和或不饱和烷基、具有1至6个碳原子的卤代烷基、具有1至6个碳原子的烷氧羰基、酰基或取代或未取代的苯基；R1和R2均不表示氢原子；n表示1或2）。该噻唑基异氰酸酯由两个前体物质产生：氨基噻唑和羰基卤化物。本发明可以提供一种生产高产率烷氧基苯甲酰胺的方法，步骤更少，也可以提供噻唑基异氰酸酯，其在尿素、氨基甲酸酯和带有噻唑环的芳香酰胺的生产中有用。
• Modifier for lithium catalysts
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0258167A2

  公开（公告）日：1988-03-02

  It has been determined that 1,2,3-trialkoxybenzenes and 1,2,4-trialkoxybenzenes can be utilized in order to increase the vinyl content of polydienes which are prepared utilizing lithium catalyst systems. For instance, it has been determined that 1,2,3-trimethoxybenzene and 1,2,4-trimethoxybenzene are very strong modifiers for utilization in such polymerizations. The utilization of the trialkoxybenzene modifiers of the present invention is highly advantageous because they promote fast polymerization rates and can be used to produce polymers having high vinyl contents.

  已确定 1,2,3-三烷氧基苯和 1,2,4-三烷氧基苯可用于增加利用锂催化剂体系制备的聚二 烯中的乙烯基含量。例如，已确定 1,2,3-三甲氧基苯和 1,2,4-三甲氧基苯是用于此类聚合反应的强改性剂。使用本发明的三烷氧基苯改性剂非常有利，因为它们能促进快速聚合，并可用于生产乙烯基含量高的聚合物。
• Segmented elastomer
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0438967A1

  公开（公告）日：1991-07-31

  It is important for tire treads to exhibit good wet skid resistance, low rolling resistance, good wear characteristics and good abrasion resistance. This is often accomplished by utilizing a blend of various rubbers in making tire tread compositions. However, some of the desirable characteristics of the individual rubbers in the blend are frequently lost on mixing. The segmented elastomers of this invention offer a unique combination of desirable characteristics for utilization in making tire tread compositions. This invention more specifically discloses a rubber polymer which has an excellent combination of properties for use in making tire treads which is comprised of: (a) a first segment which is comprised of repeat units which are derived from isoprene having a microstructure wherein there are from about 75% to about 98% 1,4-linkages and from about 2% to about 25% 3,4-linkages and wherein the first segment has a number average molecular weight which is within the range of about 25,000 to about 350,000; and (b) a second segment which is comprised of repeat units which are derived from 30 to 95 weight percent 1,3-butadiene and from 5 to 70 weight percent styrene, wherein the sum of (1) the product of 1.7 and the weight percent of styrene in the second segment and (2) the percentage of 1,2-butadiene linkages in the second segment is within the range of about 50% to about 92%, and wherein the second segment has a number average molecular weight which is within the range of about 50,000 to about 350,000.

  轮胎胎面必须具有良好的防滑性、低滚动阻力、良好的磨损特性和耐磨性。这通常是通过在轮胎胎面成分中使用各种橡胶的混合物来实现的。然而，混合橡胶中的单个橡胶的一些理想特性往往会在混合时丧失。本发明的分段弹性体提供了独特的理想特性组合，可用于制造轮胎胎面组合物。本发明更具体地公开了一种橡胶聚合物，它具有用于制造轮胎胎面的优异组合特性，由以下部分组成：(a) 第一段，由异戊二烯衍生的重复单元组成，其微观结构中 1,4-联结占约 75% 至约 98%，3,4-联结占约 2% 至约 25%，第一段的平均分子量在约 25,000 至约 350,000 之间；(b) 第二段由 30%至 95%的 1,3-丁二烯和 5%至 70%的苯乙烯的重复单元组成， 其中(1)1,3-丁二烯的重量百分比与苯乙烯的重量百分比的乘积之和为 1.7 的乘积和第二段中苯乙烯的重量百分比，以及(2) 第二段中 1，2-丁二烯链节的百分比之和在约 50% 至约 92% 的范围内，其中第二段的数均分子量在约 50,000 至约 350,000 的范围内。
• Isoprene-butadiene diblock rubber
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0761703A1

  公开（公告）日：1997-03-12

  The subject invention discloses an isoprene-butadiene diblock rubber which is particularly valuable for use in making treads for tires which have improved wear characteristics without compromising traction characteristics or rolling resistance. Said isoprene-butadiene diblock rubber is comprised of (1) a first block which is comprised of repeat units which are derived from 1,3-butadiene and (2) a second block which is comprised of repeat units which are derived from both 1,3-butadiene and isoprene, wherein the repeat units derived from isoprene and 1,3-butadiene in the second block are in an essentially random order, wherein the diblock rubber has a glass transition temperature which is within the range of about -100°C to about -70°C, and wherein the diblock rubber has a Mooney viscosity which is within the range of about 50 to about 140. In cases where the isoprene-butadiene diblock rubber of this invention is employed in automobile tires it will preferably have a second glass transition temperature which is within the range of about -50°C to about 0°C. The Mooney viscosity will preferably be within the range of about 80 to about 135 and in the case of oil extended polymers will more preferably be within the range of about 100 to about 130 before oil extension.

  本发明公开了一种异戊二烯-丁二烯二嵌体橡胶，这种橡胶特别适用于制造轮胎胎面，在不影响牵引特性或滚动阻力的情况下，改善轮胎的磨损特性。所述异戊二烯-丁二烯二嵌体橡胶由以下两部分组成：(1) 第一嵌段，该嵌段由源自 1,3-丁二烯的重复单元组成；(2) 第二嵌段，该嵌段由源自 1,3-丁二烯和异戊二烯的重复单元组成、其中二嵌段橡胶的玻璃化温度在约 -100°C 至约 -70°C 的范围内，二嵌段橡胶的门尼粘度在约 50 至约 140 的范围内。在汽车轮胎中使用本发明的异戊二烯-丁二烯二嵌橡胶时，其第二玻璃化转变温度最好在约 -50°C 至约 0°C 的范围内。门尼粘度最好在约 80 至约 135 的范围内，如果是油延伸聚合物，在油延伸之前，门尼粘度最好在约 100 至约 130 的范围内。
• Tire tread compound
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP0796898A1

  公开（公告）日：1997-09-24

  The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100°C to about -70°C, wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100°C which is within the range of about 50 to about 140, and wherein the repeat units derived from isoprene and 1,3-butadiene in the isoprene-butadiene block are in essentially random order; and (b) a second rubber selected from the group consisting of high vinyl polybutadiene rubber, styrene-isoprene-butadiene rubber, solution styrene-butadiene rubber and emulsion styrene-butadiene rubber.

  本发明公开了一种具有外圆周胎面的充气轮胎，其中所述胎面为硫硫化橡胶组合物，该组合物由 (a) 异戊二烯-丁二烯二嵌段橡胶组成，所述异戊二烯-丁二烯二嵌段橡胶由丁二烯嵌段和异戊二烯-丁二烯嵌段组成、其中所述丁二烯嵌段的平均分子量在约 25,000 至约 350,000 的范围内，其中所述异戊二烯-丁二烯嵌段的平均分子量在约 25、其中所述异戊二烯-丁二烯二嵌段聚合物在 100℃时的门尼 ML-4 粘度在约 50 至约 140 的范围内，且异戊二烯-丁二烯嵌段中由异戊二烯和 1,3-丁二烯衍生的重复单元基本上是无序的；(b) 第二种橡胶，选自高乙烯基聚丁二烯橡胶、苯乙烯-异戊二烯-丁二烯橡胶、溶液苯乙烯-丁二烯橡胶和乳液苯乙烯-丁二烯橡胶组成的组。