4,4'-dipyrrolidinobenzophenone | 95245-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-dipyrrolidinobenzophenone
• 英文别名: bis(4-(pyrrolidin-1-yl)phenyl)methanone；Bis(4-pyrrolidin-1-ylphenyl)methanone
• CAS: 95245-61-7
• 化学式: C₂₁H₂₄N₂O
• 分子量: 320.434
• InChiKey: IWMDCSLNOBDIHF-UHFFFAOYSA-N

物化性质

• 沸点：
  520.0±35.0 °C(Predicted)
• 密度：
  1.158±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  23.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4,4'-dipyrrolidinobenzophenone 在 aluminum oxide 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 5.0h， 生成 1-[4-[1-Phenyl-3-(4-pyrrolidin-1-ylphenyl)benzo[f]chromen-3-yl]phenyl]pyrrolidine
  参考文献：
  名称：

  [EN] PHOTOCHROMIC DYES AND POLYMERIC MATRIX FOR AN EFFICIENT DIMMING FILM
  [FR] PHOTOCHROMES ET MATRICE POLYMÈRE PERMETTANT D'OBTENIR UN FILM DE GRADATION EFFICACE

  摘要：

  The present disclosure relates to a photochromic molecule and uses of said molecule. The present disclosure further relates to a method of preparing a film comprising said molecule. The present disclosure also relates to a film prepared using said molecule and a device comprising said molecule. Furthermore, the present disclosure relates to a method for synthesis of said molecule.

  公开号：

  WO2022148752A2
• 作为产物：
  描述：

  四氢吡咯 、 4,4'-二氟二苯甲酮 反应 5.0h， 以83%的产率得到4,4'-dipyrrolidinobenzophenone
  参考文献：
  名称：

  [EN] PHOTOCHROMIC DYES AND POLYMERIC MATRIX FOR AN EFFICIENT DIMMING FILM
  [FR] PHOTOCHROMES ET MATRICE POLYMÈRE PERMETTANT D'OBTENIR UN FILM DE GRADATION EFFICACE

  摘要：

  The present disclosure relates to a photochromic molecule and uses of said molecule. The present disclosure further relates to a method of preparing a film comprising said molecule. The present disclosure also relates to a film prepared using said molecule and a device comprising said molecule. Furthermore, the present disclosure relates to a method for synthesis of said molecule.

  公开号：

  WO2022148752A2

文献信息

• Synthesis and spectral characterization of bisnaphthylmethyl and trinaphthylmethyl cations
  作者：Lionel Sanguinet、Robert J. Twieg、Greg Wiggers、Guilin Mao、Kenneth D. Singer、Rolfe G. Petschek

  DOI：10.1016/j.tetlet.2005.05.138

  日期：2005.8

  Cationic triarylmethane dyes containing one, two or three naphthalene moieties have been prepared. Their synthesis and preliminary spectral, nonlinear optical and theoretical characterization tire reported here. The major electronic and steric hindrance effects of the 1.4-linked naphthalene have been examined by comparison of the UV-vis absorption of the 1,4-linked and 2,6-linked series. (c) 2005 Elsevier Ltd. All rights reserved.
• Beach, Steven F.; Hepworth, John D.; Mason, Donald, Journal of the Chemical Society. Perkin transactions II, 1985, p. 107 - 110
  作者：Beach, Steven F.、Hepworth, John D.、Mason, Donald、May, Bernadette、Hallas, Geoffrey

  DOI：——

  日期：——