[Co(O2CCH3)(2,2'-bipyridine)2](sulfamate) | 1333154-82-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Co(O2CCH3)(2,2'-bipyridine)2](sulfamate)
• CAS: 1333154-82-7
• 化学式: C₂₂H₁₉CoN₄O₂*H₂NO₃S
• 分子量: 526.498
• InChiKey: LAHMIIDAUNFZPJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 钠氨基磺酸 、 cobalt(II) diacetate tetrahydrate 以 not given 为溶剂， 生成 [Co(O2CCH3)(2,2'-bipyridine)2](sulfamate) 、 [Co2(μ-hydroxo)2(μ-O2CCH3)(O2CCH3)2(2,2'-bipyridine)2](sulfamate)
  参考文献：
  名称：

  Role of hydrogen peroxide in the synthesis of nitrogen heterocycle containing cobalt complexes

  摘要：

  The reactions of Co(O2CCH3)(2)center dot 4H(2)O with the sodium salt of p-toluene sulfonic acid (NapTS) and pyridine (py) or 4-methylpyridine (4mepy) in the presence of hydrogen peroxide in methanol led to the formation of [Co(py)(3)(H2O)(3)](pTS)(2) or [Co(4mepy)(2)(H2O)(4)](pTS)(2)center dot MeOH. respectively. The coordination polymer [(Co(44'bpy)(H2O)(4))(pTS)(2)](n) (4,4'-bipyridine = 44'bpy) was obtained from the reaction of Co(O2CCH3)(2)center dot 4H(2)O with 44'bpy 44'bpy in the presence of NapTS. The reaction of Co(O2CCH3)(2)center dot 4H(2)O, 2,2'-bipyridine (22'bpy) and NapTS with hydrogen peroxide resulted in the formation of the dinuclear complex [Co-2(mu-OH)(2)(mu-O2CCH3)(O2CCH3)(2)(22'bpy)(2)](pTS). characterization of these complexes and the role of hydrogen peroxide in these reactions are discussed. Similar reactions with sodium sulfamate gave the mononuclear [Co(22'bpy)(2)(O2CCH3)]NH2SO3 center dot 2H(2)O complex and [Co-2(mu-OH)(2)(mu-O2CCH3)(O2CCH3)(2) (22'bpy)(2)](NH2SO3). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.07.010