(+/-)-9.10-dioxo-2.3.7.10ac-tetramethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene | 63018-86-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (+/-)-9.10-dioxo-2.3.7.10ac-tetramethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene
• 英文别名: (+/-)-9.10-Dioxo-2.3.7.10ac-tetramethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthren
• CAS: 63018-86-0
• 化学式: C₁₈H₂₀O₂
• 分子量: 268.356
• InChiKey: QBHAZULPRVECJR-YJBOKZPZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.98
• 重原子数：
  20.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (+/-)-9.10-dioxo-2.3.7.10ac-tetramethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene 在 1,4-二氧六环 、 sodium hydroxide 、 双氧水 作用下， 生成 (+/-)-1.3.4-trimethyl-6c-(4-methyl-2-carboxy-phenyl)-cyclohexene-(3)-carboxylic acid-(1r)
  参考文献：
  名称：

  Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison

  摘要：

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.

  DOI：

  10.1080/09585180122057
• 作为产物：
  描述：

  频哪醇 在 aluminum oxide 、 乙醇 作用下， 生成 (+/-)-9.10-dioxo-2.3.7.10ac-tetramethyl-(4arH)-1.4.4a.9.10.10a-hexahydro-phenanthrene
  参考文献：
  名称：

  A Study of the Addition Reactions of Certain Alkylated Naphthoquinones¹

  摘要：

  DOI：

  10.1021/ja01327a049