(5,10,15-tritolyl-isocorrolato)Cu(1-) | 867204-67-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (5,10,15-tritolyl-isocorrolato)Cu(1-)
• 英文别名: (TTCor)Cu(1-)
• CAS: 867204-67-9
• 化学式: C₄₀H₂₉CuN₄
• 分子量: 629.243
• InChiKey: SEOPONQMEDKTHM-BZLUFMOKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5,10,15-tris[(4-methylphenyl)corrolato]copper(III) 在 tetra-n-butylammonium perchlorate 作用下， 以 二氯甲烷 为溶剂， 生成 (5,10,15-tritolyl-isocorrolato)Cu(1-)
  参考文献：
  名称：

  Synthesis and Characterization of Free-Base, Copper, and Nickel Isocorroles

  摘要：

  A series of free-base and metalated isocorroles represented as (TT-n-iso-Cor)H-2 and (TT-n-iso-Cor)M-II, where n=5 or 10 and M = Ni or Cu, were synthesized and characterized by electrochemistry and spectroelectrochemistry in CH2Cl2 containing 0.1 M tetra-n-butylammonium perchlorate. The metalation of the free-base macrocydes with Co-II, Mn-IIII, or Zn-II was also attempted but was unsuccessful. Six isocorroles were isolated and shown to undergo two stepwise oxidations to give pi-cation radicals and dications in CH2Cl2, with the most stable products being obtained in the case of the 10-substituted derivatives. The same isocorroles could also be reduced by one or two electrons, but the initial one-electron addition products are unstable and undergo a rapid chemical reaction giving a reduced corrole or corrole-like product, which could be reoxidized to the corresponding (TTCor)M at a controlled positive potential. This series of reactions effectively illustrates an isocorrole to corrole conversion upon reduction and reoxidation and was monitored by both electrochemistry and thin-layer spectroelectrochemistry.

  DOI：

  10.1021/ic100730j