(2-((2-(dimethylamino)ethylimino)methyl)phenolato)(thiocyanato)nickel(II) | 1352299-23-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-((2-(dimethylamino)ethylimino)methyl)phenolato)(thiocyanato)nickel(II)
• CAS: 1352299-23-0
• 化学式: C₁₂H₁₅N₃NiOS
• 分子量: 308.027
• InChiKey: NXVCPKHZPNYEKQ-ANOGCNOSSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 nickel diacetate 、 6-[[2-(dimethylamino)ethylamino]methylidene]cyclohexa-2,4-dien-1-one 以 甲醇 为溶剂， 生成 (2-((2-(dimethylamino)ethylimino)methyl)phenolato)(thiocyanato)nickel(II)
  参考文献：
  名称：

  On the different coordination of NiII, ZnII and CdII cations in their model Schiff base complexes – Single crystal X-ray and solid state NMR studies

  摘要：

  Three model metal complexes: Ni(NCS)L, Zn-2(NCS)(2)L-2 and Cd-2(NCS)(2)L-2, consisting of the SCN- anion(s) and L = 2-[(2-dimethylaminoethylimino)-methyl]-phenolate, have been studied by X-ray diffraction and solid state NMR spectroscopy. The metal cations in these complexes have different coordination modes: Ni2+ is almost square-planar, the Zn2+ cation in Zn-2(NCS)(2)L-2 is pentacoordinated, whereas Cd2+ is penta- and hexacoordinated in [Cd-2(NCS)(2)L-2]. The different coordination of the metal cations influences the chemical shifts of the metal cations and also the nitrogen atoms. These chemical shifts can be correlated with the M-N and M-O bond lengths (M = Ni2+, Zn2+, Cd2+). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.09.020