cis-[Pd(OTf)2(dppbz)] | 610272-05-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: cis-[Pd(OTf)2(dppbz)]
• 英文别名: cis-[Pd(OTf)2(1,2-bis(diphenylphosphino)benzene)]
• CAS: 610272-05-4
• 化学式: C₃₂H₂₄F₆O₆P₂PdS₂
• 分子量: 851.029
• InChiKey: MAHOAILVYJQTIN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Pd(OTf)2(dppbz)] 、 1,4-二(吡啶-4-基)丁-1,3-二炔 以 二氯甲烷 为溶剂， 生成 [(Pd(1,2-bis(diphenylphosphino)benzene)(1,4-bis(4-pyridyl)butadiyne))4](triflate)8
  参考文献：
  名称：

  Study of the self-assembly reactions between the organic linker 1,4-bis(4-pyridyl)butadiyne and the metal-containing corners (diphosphine)M(II) (M=Pd, Pt; diphosphine=dppp, dppf, depe, dppbz)

  摘要：

  The diaza ligand 1,4-bis(4-pyridyl)butadiyne (L) has been used as a linker in self-assembly reactions with different diphosphine Pd(II) and Pt(II) triflates to build metallosupramolecular squares and triangles. Equilibria between triangular and square entities have been detected in most of the cases and their composition studied by multinuclear NMR spectroscopy and mass spectrometry. The self-assembly process has been shown to be strongly dependent on the conditions of the medium and the nature of the transition metal. The ability of some of these compounds to recognise inorganic anions has been investigated. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00595-3