[Ni(II)(2,2'-bipyridine)(1,2-benzenediselenolene)] | 685142-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ni(II)(2,2'-bipyridine)(1,2-benzenediselenolene)]
• CAS: 685142-49-8
• 化学式: C₁₆H₁₂N₂NiSe₂
• 分子量: 448.895
• InChiKey: LDFFJVKNBKEJPA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二甲基氧化锡 、 poly(o-phenylenediselenide) 在 NaBH₄ 作用下， 以 甲醇 为溶剂， 生成 [Ni(II)(2,2'-bipyridine)(1,2-benzenediselenolene)]
  参考文献：
  名称：

  Synthesis and characterization of diimine–diselenolene complexes of nickel and platinum: examining the influence of the chalcogenide atom

  摘要：

  [(bpy)Pt(bds)], 1, (bpy-2,2'-bipyridine,bds-1,2-benenediselenolene) was prepared in good yield by the reaction of [(bpy)PtCl2] with bdsNa(2), which was generated in situ by reduction of oligomeric [bds](n). The analogous nickel complex [(bpy)Ni(bds)] (2), was generated in a similar fashion but could not be isolated cleanly. UV-Vis and electrochemical examination of these complexes show that the substitution of selenium atoms for sulfur atoms found in the related dithiolene complexes [(bpy)Pt(bdt)] (3), and [(bpy)Ni(bdt)] (4) (bdt= 1,2-benzenedithiolene) results in a small, but significant, alteration of the optical and electronic properties of this class of complexes. 1 was structurally characterized as both its CH2Cl2 solvate (P2(1)/n - a=8.5298(10) Angstrom, b=11.3461(2), c=19.1864(2), beta=99.309(10)degrees, V=1832.40(4) Angstrom(3), Z=4) and its DMSO solvate (P2(1)/c-a=11.1725(10) Angstrom, b=20.7304(10) Angstrom, c=8.3882(10) Angstrom, beta=99.926(10), V=1913.71(3) Angstrom(3), Z=4). With the exception of the incorporation of lattice solvent, both structures of 1 are essentially identical to that observed for 3 and 4 at both the molecular and supramolecular level. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.09.004