(NBu4)[Pt(C6F5)3(PPy3)] | 651351-13-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (NBu4)[Pt(C6F5)3(PPy3)]
• 英文别名: (NBu4)[Pt(C6F5)3(P(2-pyridyl)3)]；1,2,3,4,5-pentafluorobenzene-6-ide;platinum(2+);tetrabutylazanium;tripyridin-2-ylphosphane
• CAS: 651351-13-2
• 化学式: C₁₆H₃₆N*C₃₃H₁₂F₁₅N₃PPt
• 分子量: 1203.98
• InChiKey: GYAMNBBIXKDNQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 (NBu4)[Pt(C6F5)3(PPy3)] 在 AgNO₃ 作用下， 以 丙酮 为溶剂， 以45%的产率得到[(C6F5)3Pt(μ-P(2-pyridyl)3)Rh(CO)2]
  参考文献：
  名称：

  Anionic Platinum Complexes with 2-Pyridylphosphines as Ligands for Rhodium:  Synthesis of Zwitterionic Pt−Rh Organometallic Compounds

  摘要：

  Bimetallic zwitterionic platinum(II)-rhodium(I) complexes of the type [(C6F5)(3)Pt(mu-PPynPh3-n)Rh(CO)(2))] and [(C6F5)(3)Pt(mu-PPynPh3-n)Rh(diene))] (n = 2, 3; Py = 2-pyridyl) have been prepared. The P end of the bridging ligands (mu-PPynPh3-n) is always coordinated to the Pt center, while the N-donor ends chelate the Rh atom, giving metallacycles comparable to pyrazolylborate-Rh complexes. These metallacycles can adopt two conformations, either with the Pt complex in pseudoaxial position approaching the Rh center or with the Pt complex in a remote position. The preferred conformation depends on the steric hindrance at the rhodium center. In less sterically demanding Rh-carbonyl complexes the Pt moiety gets close to the Rh moiety as this brings closer the opposite charges of the zwitterion. For diene complexes mixtures of conformers are obtained. The X-ray structures of [(C6F5)(3)Pt(mu-PPhPy2)Rh(COD)] (COD = 1,5-cyclooctadiene) and [(C6F5)(3)Pt(mu-PPhPy2)Rh(CO)(2)] are reported.

  DOI：

  10.1021/ic034863f
• 作为产物：
  描述：

  {(C4H9)4N}{Pt(C6F5)3(tetrahydrothiophene)} 、 三（2-吡啶基）膦 以 乙醇 为溶剂， 以81%的产率得到(NBu4)[Pt(C6F5)3(PPy3)]
  参考文献：
  名称：

  Anionic Platinum Complexes with 2-Pyridylphosphines as Ligands for Rhodium:  Synthesis of Zwitterionic Pt−Rh Organometallic Compounds

  摘要：

  Bimetallic zwitterionic platinum(II)-rhodium(I) complexes of the type [(C6F5)(3)Pt(mu-PPynPh3-n)Rh(CO)(2))] and [(C6F5)(3)Pt(mu-PPynPh3-n)Rh(diene))] (n = 2, 3; Py = 2-pyridyl) have been prepared. The P end of the bridging ligands (mu-PPynPh3-n) is always coordinated to the Pt center, while the N-donor ends chelate the Rh atom, giving metallacycles comparable to pyrazolylborate-Rh complexes. These metallacycles can adopt two conformations, either with the Pt complex in pseudoaxial position approaching the Rh center or with the Pt complex in a remote position. The preferred conformation depends on the steric hindrance at the rhodium center. In less sterically demanding Rh-carbonyl complexes the Pt moiety gets close to the Rh moiety as this brings closer the opposite charges of the zwitterion. For diene complexes mixtures of conformers are obtained. The X-ray structures of [(C6F5)(3)Pt(mu-PPhPy2)Rh(COD)] (COD = 1,5-cyclooctadiene) and [(C6F5)(3)Pt(mu-PPhPy2)Rh(CO)(2)] are reported.

  DOI：

  10.1021/ic034863f