5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) bromide | 652970-86-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) bromide
• CAS: 652970-86-0
• 化学式: Br*C₁₄H₂₂AuN₄
• 分子量: 523.226
• InChiKey: JAONXDMLDCWFHZ-MNNCVMEPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium perrhenate 、 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) bromide 以 乙醇 为溶剂， 以82%的产率得到5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) perrhenate
  参考文献：
  名称：

  Crystal and molecular structure of [Au(C14H22N4)]ReO4

  摘要：

  Perrhenate of the tetraazamacrocyclic complex of gold(III) [Au(C14H22N4)]ReO4 is synthesized. The crystal structure of the compound is determined by single crystal X-ray diffraction. The crystallographic data are as follows: D degrees = 7.733(2) , b = 11.368(2) , c = 11.685(2) , alpha = 116.23A degrees, beta = 104.26A degrees, gamma = 94.96A degrees; V = 870.3(3) (3), space group P(-1), Z = 2, d (calc) = 2.647 g/cm(3), R = 0.0245. The packing of the complex is comprised of double stacks of cations and chains of anions linked into two-dimensional layers due to weak intermolecular interactions (non-classical hydrogen bonds C-HaEuro broken vertical bar O, C-HaEuro broken vertical bar Au, C-HaEuro broken vertical bar pi and the AuaEuro broken vertical bar Au contacts). The thermal decomposition of the obtained compound in the hydrogen atmosphere is studied. According to the powder X-ray diffraction data, the product of the reduction of the synthesized salt is a mixture of nanocrystalline phases of Re and Au with the coherent-scattering regions of 17 nm and 13 nm respectively.

  DOI：

  10.1134/s0022476615040289
• 作为产物：
  描述：

  bis(1,2-diaminoethane)gold(III)(3+) 、 氢溴酸 、 乙酰丙酮 以 not given 为溶剂， 以30%的产率得到5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) bromide
  参考文献：
  名称：

  不饱和金（III）四氮杂配合物：合成，结构和性质

  摘要：

  概括了有关含有两个五元和一个或两个六元不饱和螯合环的多螯合金（III）四氮杂配合物的合成和理化研究的数据。

  DOI：

  10.1134/s1070328410010021

文献信息

• Secondary interactions in the crystal structure of heterovalent 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III) dibromoaurite(I)
  作者：V. A. Afanas’eva、L. A. Glinskaya、R. F. Klevtsova、I. V. Mironov

  DOI：10.1134/s1070328411040014

  日期：2011.5

  [Au(C14H22N4)][AuBr2] with two types of gold atoms (Au(III) and Au(I)) was obtained. In the cation 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,6,11,13-tetraenatogold(III), the Au atom is coordinated by four N atoms of the tetraazamacrocyclic amide ligand to make up a distorted square. The dibromoaurite(I) anion is linear. The conformation and packing of the structure is determined and stabilized by weak

  得到具有两种金原子（Au（III）和Au（I））的配合物[Au（C 14 H 22 N 4）] [AuBr 2 ]。在阳离子5,7,12,14-四甲基-1,4,8,11-四氮杂环十四烷基-4,6,11,13-四烯丙基金（III）中，Au原子由四氮杂大环酰胺配体的四个N原子配位组成一个扭曲的正方形。二溴金红石（I）阴离子是线性的。结构的构象和堆积是通过弱分子间氢键CH…Br和CH…Au，亲金相互作用Au（I）…Au（III）和配位键Au…N来确定和稳定的。