1,2-di([2,2'-bithiophen]-5-yl)-N1,N2-bis(4-butylphenyl)ethene-1,2-diamine | 1201806-35-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 1,2-di([2,2'-bithiophen]-5-yl)-N1,N2-bis(4-butylphenyl)ethene-1,2-diamine
• CAS: 1201806-35-0
• 化学式: C₃₈H₃₈N₂S₄
• 分子量: 650.997
• InChiKey: ANBPMMUSEZYHCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.0
• 重原子数：
  44.0
• 可旋转键数：
  14.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  24.06
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,2-di([2,2'-bithiophen]-5-yl)-N1,N2-bis(4-butylphenyl)ethene-1,2-diamine 在 对苯醌 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以98%的产率得到1,2-di([2,2'-bithiophen]-5-yl)-N1,N2-bis(4-butylphenyl)ethane-1,2-diimine
  参考文献：
  名称：

  Electropolymerization of an N-Heterocyclic Carbene−Gold(I) Complex

  摘要：

  We report the first example of a polymer in which each monomer contains an N-heterocyclic carbene (NHC) orthogonally connected to its main chain. A polymerizable imidazolylidene-AuCl complex containing pendant bithiophene moieties was prepared in a high-yield multistep procedure. Oxidative electropolymerization of this monomer afforded the desired polymer, (Au[NHC]Cl)(n), which was characterized via electrochemical studies as well as X-ray photoelectron and UV-vis spectroscopy.

  DOI：

  10.1021/ja908969q
• 作为产物：
  描述：

  1-([2,2'-bithiophen]-5-yl)-N-(4-butylphenyl)methanimine 在 sodium cyanide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以75%的产率得到1,2-di([2,2'-bithiophen]-5-yl)-N1,N2-bis(4-butylphenyl)ethene-1,2-diamine
  参考文献：
  名称：

  Electropolymerization of an N-Heterocyclic Carbene−Gold(I) Complex

  摘要：

  We report the first example of a polymer in which each monomer contains an N-heterocyclic carbene (NHC) orthogonally connected to its main chain. A polymerizable imidazolylidene-AuCl complex containing pendant bithiophene moieties was prepared in a high-yield multistep procedure. Oxidative electropolymerization of this monomer afforded the desired polymer, (Au[NHC]Cl)(n), which was characterized via electrochemical studies as well as X-ray photoelectron and UV-vis spectroscopy.

  DOI：

  10.1021/ja908969q