trans-4,4,4-Trichlor-buten-(2)-saeure-(1) | 5464-74-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: trans-4,4,4-Trichlor-buten-(2)-saeure-(1)
• 英文别名: gamma,gamma,gamma-Trichlorocrotonic acid；(E)-4,4,4-trichlorobut-2-enoic acid
• CAS: 5464-74-4
• 化学式: C₄H₃Cl₃O₂
• 分子量: 189.426
• InChiKey: NXERUYGRZMHUMK-OWOJBTEDSA-N

物化性质

• 熔点：
  82-83 °C
• 沸点：
  309.3±42.0 °C(Predicted)
• 密度：
  1.618±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  trans-4,4,4-Trichlor-buten-(2)-saeure-(1) 在 吡啶 、 铜 作用下， 生成 3,3,4,4-Tetrachlor-hexadien-1,5-dicarbonsaeure-1,6
  参考文献：
  名称：

  Yagupol'skii,L.M.; Chaika,E.A., Journal of Organic Chemistry USSR (English Translation), 1966, vol. 2, p. 1716 - 1718

  摘要：

  DOI：
• 作为产物：
  描述：

  4-(三氯甲基)-2-氧杂环丁酮 生成 trans-4,4,4-Trichlor-buten-(2)-saeure-(1)
  参考文献：
  名称：

  Darstellung und Reaktionen von ?-Trichlormethyl-?-lactonen

  摘要：

  DOI：

  10.1007/bf00902408

文献信息

• Changing stereoselectivity and regioselectivity in copper(<scp>i</scp>)-catalyzed 5-<i>exo</i> cyclization by chelation and rigidity in aminoalkyl radicals: synthesis towards diverse bioactive N-heterocycles
  作者：Sandhya Sadanandan、Dharmendra Kumar Gupta

  DOI：10.1039/c9nj05166j

  日期：——

  Chelation, rigidity and carbon-radical positions in aminoalkyl precursors disturb the usual 2,4-trans diastereoselectivity and 5-exo mode in Cu(i)-catalyzed ATRC.

  螯合、刚性和氨基烷基前体中的碳自由基位置会干扰通常的2,4-trans 反式选择性和5-exo 模式在Cu(i)-催化的ATRC中。
• Synthesen von polyhalogenierten Butyrylchloriden, Vorläufern der pyrethroiden Haloketene
  作者：Pierre Martin、Eginhard Steiner、Daniel Belluš

  DOI：10.1002/hlca.19800630722

  日期：1980.10.29

  Synthesis of Polyhalogenated Butyryl Chlorides, Precursors of Pyrethroid Haloketenes

  拟除虫菊酯卤代烷的前体多卤代丁酰氯的合成
• Supported catalyst containing active titanium in the homo, co-, and ter-polymerization of olefin-unsaturated compounds
  申请人：Masi Francesco

  公开号：US20060014631A1

  公开（公告）日：2006-01-19

  The present invention relates to a supported catalyst containing titanium, its preparation and it use in the homo-, co-, and ter-polymerization of olefin-unsaturated compounds. The present invention also relates to a catalytic system comprising a supported catalyst based on titanium and a co-catalyst selected from organo-derivatives of aluminum. More, specifically, the present invention relates to catalyst supported on silica, obtained by reacting a titanium halocarboxylate and a magnesium halocarboxylate with an aluminum chloroakylderivative, in the presente of a carrier consisting of high porosity silica. The above reaction essentially takes place in the pores of the silica itself.

  本发明涉及一种含钛的支撑催化剂，其制备及其在烯烃-不饱和化合物的同聚、共聚和三聚中的使用。本发明还涉及一种催化系统，包括基于钛的支撑催化剂和有机铝衍生物的共催化剂。更具体地说，本发明涉及在高孔隙度硅胶载体的存在下，通过反应钛卤代羧酸盐和镁卤代羧酸盐与氯代烷基铝衍生物获得的硅胶支撑催化剂。上述反应主要发生在硅胶孔道内。
• Titanium catalysts, preparation and use in co- and ter-polymerization of alpha-olefins
  申请人：——

  公开号：US20040143127A1

  公开（公告）日：2004-07-22

  Titanium complex having general formula (1) (RCOO) n TiX p wherein R is a monofunctional hydrocarbyl radical having from 1 to 20 carbon atoms and a number of halogen atoms, selected from fluorine, chlorine and bromine, preferably chlorine, ranging from 1 to 6; X is chlorine, bromine or a beta-dicarbonyl group such as acetylacetone (AcAc), formylacetone, benzoylacetone, dibenzoylmethane; p+n=2, 3, 4, preferably p+n=3; n is greater than or equal to 1. The preparation of the above complex and its use in the co- and ter-polymerization of &agr;-olefins, are also described.

  具有一般式（1）（RCOO）nTiXp的钛配合物，其中R是具有1至20个碳原子和一定数量的卤素原子（选择自氟、氯和溴，优选氯），范围为1至6的单官能羟基烃基基团；X是氯、溴或β-二羰基基团，例如乙酰丙酮（AcAc）、甲酰丙酮、苯甲酰丙酮、二苯甲酮；p+n=2、3、4，优选p+n=3；n大于等于1。还描述了上述配合物的制备及其在α-烯烃的共聚和三聚中的应用。
• PROCESS FOR MAKING AN ETHYLENE ELASTOMER WITH LONG CHAIN BRANCHING FOR USE IN ANTI-VIBRATION APPLICATIONS
  申请人：Lion Copolymer Geismar, LLC

  公开号：EP3026070A1

  公开（公告）日：2016-06-01

  A process and the resultant product from the process for continuously making a blend of a terpolymer and a tetrapolymer utilizing ethylene, propylene, and non-conjugated dienes. This process allows for the creation of products with high diene contents and broad molecular weight distributions while utilizing a continuous flow reactor and a known catalyst. The process allows for these products to be made without gelling or fouling of the reactor, which are problems known in the art.

  一种利用乙烯、丙烯和非共轭二烯连续制造三元共聚物和四元共聚物混合物的工艺及由此产生的产品。这种工艺可以利用连续流动反应器和已知催化剂制造出高二烯含量和宽分子量分布的产品。该工艺在制造这些产品时不会出现反应器胶凝或堵塞的问题，而这些都是本领域已知的问题。