2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid | 54797-48-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: 2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid
• 英文别名: 2-Hydroxy-6-oxo-6-phenylhexa-2.4-diensaeure
• CAS: 54797-48-7
• 化学式: C₁₂H₁₀O₄
• 分子量: 218.209
• InChiKey: RDRDHXDYMGUCKE-AFDHTILLSA-N

物化性质

• 沸点：
  409.8±45.0 °C(Predicted)
• 密度：
  1.313±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.95
• 重原子数：
  16.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid 在 HOPDA reducing enzyme III 还原型辅酶II(NADPH)四钠盐 作用下， 以 水 为溶剂， 反应 1.0h， 生成 2,6-diketo-6-phenylhexanoic acid
  参考文献：
  名称：

  Omori, Toshio; Ishigooka, Hiroshi; Minoda, Yasuji, Agricultural and Biological Chemistry, 1986, vol. 50, # 6, p. 1513 - 1518

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3-二羟基联苯 在 biphenyl-2,3-diol 1,2-dioxygenase potassium phosphate 作用下， 反应 0.67h， 生成 2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid
  参考文献：
  名称：

  Omori, Toshio; Ishigooka, Hiroshi; Minoda, Yasuji, Agricultural and Biological Chemistry, 1986, vol. 50, # 6, p. 1513 - 1518

  摘要：

  DOI：

文献信息

• Process for Producing Picolinic Acid Compounds
  申请人：Shindo Kazutoshi

  公开号：US20080254519A1

  公开（公告）日：2008-10-16

  The present invention relates to a method for producing a picolinic acid compound. Specifically, the present invention relates to a method for producing a picolinic acid compound, which comprises reacting an aromatic compound that contains a phenyl group represented by the following formula (I), (II), or (III) with aromatic ring dioxygenase, aromatic ring dihydrodiol dehydrogenase, and aromatic ring diol dioxygenase, and obtaining a picolinic acid compound (I′), (II′), or (III′). wherein, H1 is an optionally substituted heterocyclic group, A1 is a single bond or an optionally substituted C 1-4 alkylene group or alkenylene group, P2 is an optionally substituted phenyl group, and C1 is an optionally substituted cyclic hydrocarbon group (excluding a phenyl group), and where formula II does not represent diphenylacetylene.

  本发明涉及一种生产吡啶甲酸化合物的方法。具体而言，本发明涉及一种生产吡啶甲酸化合物的方法，包括将含有以下式(I)、(II)或(III)所代表的苯基的芳香化合物与芳香环二氧化酶、芳香环二羟基二氢化物脱氢酶和芳香环二醇二氧化酶反应，从而获得吡啶甲酸化合物(I′)、(II′)或(III′)。其中，H1是可选取代的杂环基团，A1是单键或可选取代的C1-4烷基或烯基基团，P2是可选取代的苯基，C1是可选取代的环烃基团（不包括苯基），式II不代表二苯乙炔。
• PCB-Degrading recombinant bacterium, product for the bioremediation and method of bioremediation
  申请人：Michael Seeger Pfeiffer

  公开号：US20080318302A1

  公开（公告）日：2008-12-25

  A recombinant bacterium capable to completely degrade or mineralize pollutants such as polychlorobiphenyls (PCBs), which corresponds to Wautersia eutropha strain JMS34, deposited under the access number NRRL B-30817 a product for the bioremediation of environments contaminated with PCBs, where the product includes a bacterial inoculum of this recombinant strain and a method for the bioremediation of environments contaminated with PCBs, which uses this product for the bioremediation.
• US7989194B2
  申请人：——

  公开号：US7989194B2

  公开（公告）日：2011-08-02
• Omori, Toshio; Ishigooka, Hiroshi; Minoda, Yasuji, Agricultural and Biological Chemistry, 1986, vol. 50, # 6, p. 1513 - 1518
  作者：Omori, Toshio、Ishigooka, Hiroshi、Minoda, Yasuji

  DOI：——

  日期：——