[cobalt(II)(N-(2-mesitylenesulfonyl)-2-amino-3-picoline(1-))2((2,2'-bipyridine))] | 913745-45-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [cobalt(II)(N-(2-mesitylenesulfonyl)-2-amino-3-picoline(1-))2((2,2'-bipyridine))]
• CAS: 913745-45-6
• 化学式: C₄₀H₄₂CoN₆O₄S₂
• 分子量: 793.936
• InChiKey: SKKDOQBGHMDHKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 N-(3-methyl-2-pyridyl)mesitylenesulfonamide 、 钴 在 Et₄NClO₄ 作用下， 以 乙腈 为溶剂， 生成 [cobalt(II)(N-(2-mesitylenesulfonyl)-2-amino-3-picoline(1-))2((2,2'-bipyridine))]
  参考文献：
  名称：

  Electrochemical synthesis and structural characterization of heteroleptic cobalt(II) complexes of N-2-pyridyl sulfonamide ligands

  摘要：

  Neutral heteroleptic cobalt complexes [CoL2L'] (L' = 2,2'-bipyridine or 1,10-phenanthroline) with the anionic form of a series of methyl-substituted N-2-pyridylsulfonamide ligands (HL) have been synthesized by the electrochemical oxidation of the metal in an acetonitrile solution of the sulfonamide ligand and the corresponding coligand L'. The compounds were characterized by microanalysis, vibrational and electronic spectroscopy and some examples by single-crystal X-ray diffraction. The crystal structures of the compounds show the metal in a distorted octahedral geometry, [N6] or [N4O2], that depends on the position of the substituent on the pyridine ring. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.03.004