1,2,4,5-四巯基苯四钠 | 129178-69-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2,4,5-四巯基苯四钠
• 英文名称: tetrasodium 1,2,4,5-tetramercaptobenzene
• CAS: 129178-69-4
• 化学式: C₆H₂S₄*4Na
• 分子量: 294.305
• InChiKey: VQRKLLPJTPPURR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -1.69
• 重原子数：
  11.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  bis(η5-trimethylsilylcyclopentadienyl)titanium(IV)dichloride 、 1,2,4,5-四巯基苯四钠 以 四氢呋喃 为溶剂， 以55%的产率得到tetrakis(η5-trimethylsilylcyclopentadienyl)(μ,η2,η2-1,2,4,5-benzenetetrathiolato)dititanium(IV)
  参考文献：
  名称：

  Koepf, H.; Balz, H., Journal of Organometallic Chemistry, 1990, vol. 387, p. 77 - 82

  摘要：

  DOI：

文献信息

• “Bis” and “tris” [(2-bis (methylthio) methylene) - [1,3] benzodithioles] as new donors
  作者：Yves Gimbert、Alec Moradpour

  DOI：10.1016/s0040-4039(00)93490-7

  日期：1991.9

  2,6-Bis (bis (methylthio) methylene) - benzo [1,2-d:4,5-d'] bis [1.3] dithiole 5 and 2,5,8-Tris (bis (methylthio) methylene) - benzo [1,2-d:3,4-d':5,6-d''] tris [1,3] dithiole 6 have been prepared and their electrochemical properties in solution have been investigated.
• Benzol-1,2,4,5-tetrathiolato-Zweikernkomplexe der 1,1′-Bis(trimethylsilyl)metallocene der Titantriade—Synthese und Strukturbestimmung von [(η5-Me3SiC5H4)2TiS2]2C6H2 und [(η5-Me3SiC5H4)2HfS2]2C6H2
  作者：H. Balz、H. Köpf、J. Pickardt

  DOI：10.1016/0022-328x(91)80199-t

  日期：1991.10

  The reaction of tetrasodium 1,2,4,5-tetramercaptobenzene with the 1,1'-bis(trimethylsilyl)metallocene dichlorides M(eta-5-C5H4R)2Cl2 (R = Si(CH3)3; M = Ti, 1a; Zr, 1b; Hf, 1c) gives the new dinuclear chelate-bridged complexes (eta-5-C5H4R)2MS2C6H2S2M(eta-5-C5H4R)2 (R = Si(CH3)3; M = Ti, 3a; Zr, 3b; Hf, 3c), which were characterized by IR, H-1 NMR and mass spectroscopy. The structures of 3a and 3c have been determined by X-ray diffraction analyses. The bridging MS2C6H2S2M moieties are in chair-like conformations with the MS2 planes inclined by 47-degrees for 3a and 52-degrees for 3c with respect to the S2C6S2 plane. Both compounds crystallize triclinic, space group P1BAR, with two crystallographically independent centrosymmetric molecules in the unit cell; lattice parameters for 3a are a 1174.7(5), b 1355.9(7), c 1475.9(11) pm, alpha 90.67(8), beta 97.13(8), gamma 98.03(5)-degrees; for 3c a 1188.6(3), b 1363.9(7), c 1519.6(9) pm, alpha 91.14(6), beta 98.37(5), gamma 98.68(3)-degrees.
• Balz, Hellfried; Koepf, Hartmut; Lange, Katharina, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 65, # 1.4, p. 185 - 188
  作者：Balz, Hellfried、Koepf, Hartmut、Lange, Katharina、Pickardt, Joachim

  DOI：——

  日期：——