monooxalatomonohydrazinenickel(II) monohydrate | 90551-12-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: monooxalatomonohydrazinenickel(II) monohydrate
• CAS: 90551-12-5
• 化学式: C₂O₄*H₂O*H₄N₂*Ni
• 分子量: 196.77
• InChiKey: XAWGMRWXVHSIBE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -5.52
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  163.8
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  在 K₂C₂O₄ 作用下， 以 水 为溶剂， 生成 monooxalatomonohydrazinenickel(II) monohydrate
  参考文献：
  名称：

  Mishra, H. C.; Mishra, G.; Choubey, L. N., Journal of the Indian Chemical Society, 1983, vol. 60, p. 521 - 523

  摘要：

  DOI：

文献信息

• A new 3-D Ni 2+ coordination polymer constructed from C 2 O 4 2− and N 2 H 4 : Synthesis, structure and magnetic property
  作者：Yan-Ning Wang、Qing-Feng Yang、Qi-Sheng Huo、Jie-Hui Yu、Ji-Qing Xu

  DOI：10.1016/j.poly.2017.03.063

  日期：2017.7

  simple self-assembly of Ni 2+ , H 2 C 2 O 4 and N 2 H 4 created a new 3-D Ni 2+ coordination polymer, [Ni(C 2 O 4 )(N 2 H 4 )]·H 2 O (C 2 O 4 2− = oxalate, N 2 H 4 = hydrazine) 1 , in which C 2 O 4 2− ligands link Ni 2+ ions into a left-hand helical Ni(C 2 O 4 ) chain, while N 2 H 4 extends the Ni(C 2 O 4 ) chains into a 3-D network with a 10 3 topology. A magnetic susceptibility study indicates that between

  在水热条件下，Ni 2+，H 2 C 2 O 4和N 2 H 4的简单自组装产生了新的3-D Ni 2+配位聚合物[Ni（C 2 O 4）（N 2 H 4） ）]·H 2 O（C 2 O 4 2- =草酸盐，N 2 H 4 =肼）1，其中C 2 O 4 2-配体将Ni 2+离子连接到左侧螺旋Ni（C 2 O 4）链，而N 2 H 4将Ni（C 2 O 4）链扩展为具有10 3拓扑的3-D网络。磁化率研究表明，在相邻的Ni 2+中心之间，存在反铁磁相互作用。
• Controllable synthesis of NiC2O4·2H2O nanorods precursor and applications in the synthesis of nickel-based nanostructures
  作者：Wei-Guo Tian、Pan-Pan Wang、Ling Ren、Gen-Ban Sun、Ling-Na Sun、Kai Yang、Bing-Qing Wei、Chang-Wen Hu

  DOI：10.1016/j.jssc.2007.09.036

  日期：2007.12

  A controllable synthesis of NiC2O4 center dot 2H(2)O nanorods precursor was obtained via the microemulsion-mediated solvothermal method and a further synthesis of beta-Ni(OH)(2) nanorods, nickel oxide (NiO) sub-microtubes, Ni nanospheres and flower-like nickel complexes nanostructures by using the precursor. The morphologies and crystalline structures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and the X-ray powder diffraction (XRD). The morphologies and sizes of the precursors can be readily tuned by adjusting experimental parameters of the reverse microemulsion system. The synthesized beta-Ni(OH)(2) nanorods composed of fine nanosheets shown excellent electrochemical performance as an electrode material in rechargeable battery systems. (c) 2007 Elsevier Inc. All rights reserved.