7-dodecyl-7H-dinaphtho[2,3-b:2',3'-h]carbazole | 1404191-40-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 7-dodecyl-7H-dinaphtho[2,3-b:2',3'-h]carbazole
• 英文别名: 16-Dodecyl-16-azaheptacyclo[15.12.0.02,15.04,13.06,11.019,28.021,26]nonacosa-1(29),2,4,6,8,10,12,14,17,19,21,23,25,27-tetradecaene；16-dodecyl-16-azaheptacyclo[15.12.0.02,15.04,13.06,11.019,28.021,26]nonacosa-1(29),2,4,6,8,10,12,14,17,19,21,23,25,27-tetradecaene
• CAS: 1404191-40-7
• 化学式: C₄₀H₄₁N
• 分子量: 535.772
• InChiKey: HNHFZOCAAODQBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.9
• 重原子数：
  41
• 可旋转键数：
  11
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  7-dodecyl-5H-dinaphtho[2,3-b:2',3'-h]carbazole-5,9,14,17(7H)-tetraone 在 四溴化碳 、 氢化铝 、 mercury dichloride 作用下， 以 环己醇 为溶剂， 反应 3.0h， 以78%的产率得到7-dodecyl-7H-dinaphtho[2,3-b:2',3'-h]carbazole
  参考文献：
  名称：

  N-Alkyldinaphthocarbazoles, Azaheptacenes, for Solution-Processed Organic Field-Effect Transistors

  摘要：

  Substituted N-alkyldinaphthocarbazoles were synthesized using a key double Diets-Alder reaction. The angular nature of the dinaphthocarbazole system allows for increased stability of the conjugated system relative to linear analogues. The N-alkyldinaphthocarbazoles were characterized by UV-vis absorption and fluorescence spectroscopy as well as cyclic voltammetry. X-ray structure analysis based on synchrotron X-ray powder diffraction revealed that the N-dodecyl-substituted compound was oriented in an intimate herringbone packing motif, which allowed for p-type mobilities of 0.055 cm(2) V-1 s(-1) from solution-processed organic field-effect transistors.

  DOI：

  10.1021/ja3082582

文献信息

• <i>N</i>-Alkyldinaphthocarbazoles, Azaheptacenes, for Solution-Processed Organic Field-Effect Transistors
  作者：Toan V. Pho、Jonathan D. Yuen、Joshua A. Kurzman、Braden G. Smith、Maosheng Miao、Wesley T. Walker、Ram Seshadri、Fred Wudl

  DOI：10.1021/ja3082582

  日期：2012.11.7

  Substituted N-alkyldinaphthocarbazoles were synthesized using a key double Diets-Alder reaction. The angular nature of the dinaphthocarbazole system allows for increased stability of the conjugated system relative to linear analogues. The N-alkyldinaphthocarbazoles were characterized by UV-vis absorption and fluorescence spectroscopy as well as cyclic voltammetry. X-ray structure analysis based on synchrotron X-ray powder diffraction revealed that the N-dodecyl-substituted compound was oriented in an intimate herringbone packing motif, which allowed for p-type mobilities of 0.055 cm(2) V-1 s(-1) from solution-processed organic field-effect transistors.