dichloro(1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane)platinum(II) | 177955-60-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dichloro(1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane)platinum(II)
• 英文别名: dichloroplatinum;2-diphenylphosphanyloxypropyl(diphenyl)phosphane
• CAS: 177955-60-1
• 化学式: C₂₇H₂₆Cl₂OP₂Pt
• 分子量: 694.436
• InChiKey: JEMSPJKPCZKSIQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dichloro(1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane)platinum(II) 、 氢气 以 四氢呋喃 为溶剂， 以70%的产率得到dihydrido(1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane)platinum(II)
  参考文献：
  名称：

  Definitive Evidence for a Pairwise Addition of Hydrogen to a Platinum Bis(phosphine) Complex Using Parahydrogen-Induced Polarization

  摘要：

  Through the use of parahydrogen-induced polarization (PHIP), conclusive evidence has been obtained that H-2 addition to Pt(Ph(2)PCH(2)CH(Me)OPPh(2)) proceeds in a concerted, pairwise manner. PHIP has also been used in. conjunction with a 2D HMQC sequence to obtain P-31 and Pt-195 NMR spectra from submilligram samples in 2-5 min.

  DOI：

  10.1021/om960295i
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane 以 二氯甲烷 为溶剂， 以60%的产率得到dichloro(1,3-bis(diphenylphosphino)-2-methyl-1-oxapropane)platinum(II)
  参考文献：
  名称：

  Definitive Evidence for a Pairwise Addition of Hydrogen to a Platinum Bis(phosphine) Complex Using Parahydrogen-Induced Polarization

  摘要：

  Through the use of parahydrogen-induced polarization (PHIP), conclusive evidence has been obtained that H-2 addition to Pt(Ph(2)PCH(2)CH(Me)OPPh(2)) proceeds in a concerted, pairwise manner. PHIP has also been used in. conjunction with a 2D HMQC sequence to obtain P-31 and Pt-195 NMR spectra from submilligram samples in 2-5 min.

  DOI：

  10.1021/om960295i

文献信息

• Millar, Susan P.; Jang, Meehae; Lachicotte, Rene J., Inorganica Chimica Acta, 1998, vol. 270, # 1-2, p. 363 - 375
  作者：Millar, Susan P.、Jang, Meehae、Lachicotte, Rene J.、Eisenberg, Richard

  DOI：——

  日期：——