7-(2-Methoxy-benzyl)-1,4,10-trioxa-7,13-diaza-cyclopentadecane | 211795-61-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 7-(2-Methoxy-benzyl)-1,4,10-trioxa-7,13-diaza-cyclopentadecane
• 英文别名: 7-[(2-Methoxyphenyl)methyl]-1,4,10-trioxa-7,13-diazacyclopentadecane；7-[(2-methoxyphenyl)methyl]-1,4,10-trioxa-7,13-diazacyclopentadecane
• CAS: 211795-61-8
• 化学式: C₁₈H₃₀N₂O₄
• 分子量: 338.447
• InChiKey: PZJBYLPXVZMCHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  7-(2-Methoxy-benzyl)-1,4,10-trioxa-7,13-diaza-cyclopentadecane 以 甲苯 、 正丁醇 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  A squaraine-based sodium selective fluorescent chemosensor

  摘要：

  A novel squaraine with a lariat-crown ether cation-receptor unit was synthesized and shown to selectively respond to Na+ ions in polar protic solvents. The selectivity of the novel ligand, together with the impressive spectroscopic properties of squaraines yields a promising chemosensor, (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)01165-4
• 作为产物：
  描述：

  2-甲氧基氯化苄 、 1,7-偶氮-15-冠-5 以52%的产率得到7-(2-Methoxy-benzyl)-1,4,10-trioxa-7,13-diaza-cyclopentadecane
  参考文献：
  名称：

  A squaraine-based sodium selective fluorescent chemosensor

  摘要：

  A novel squaraine with a lariat-crown ether cation-receptor unit was synthesized and shown to selectively respond to Na+ ions in polar protic solvents. The selectivity of the novel ligand, together with the impressive spectroscopic properties of squaraines yields a promising chemosensor, (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)01165-4

文献信息

• A squaraine-based sodium selective fluorescent chemosensor
  作者：Umut Oguz、Engin U. Akkaya

  DOI：10.1016/s0040-4039(98)01165-4

  日期：1998.8

  A novel squaraine with a lariat-crown ether cation-receptor unit was synthesized and shown to selectively respond to Na+ ions in polar protic solvents. The selectivity of the novel ligand, together with the impressive spectroscopic properties of squaraines yields a promising chemosensor, (C) 1998 Elsevier Science Ltd. All rights reserved.