(1,4-dideuterobutyl)benzene | 133817-41-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (1,4-dideuterobutyl)benzene
• 英文别名: 1,4-dideutero-1-butylbenzene；1,4-Dideuteriobutylbenzene
• CAS: 133817-41-1
• 化学式: C₁₀H₁₄
• 分子量: 136.205
• InChiKey: OCKPCBLVNKHBMX-COMABECVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯乙烯 、 乙基溴化镁 在 二氯二茂锆 、 氘代硫酸 作用下， 生成 (1,4-dideuterobutyl)benzene
  参考文献：
  名称：

  Takahashi, Tamotsu; Seki, Takashi; Nitto, Yu, Journal of the American Chemical Society, 1991, vol. 113, # 16, p. 6266 - 6268

  摘要：

  DOI：

文献信息

• Cyclomagnesation of Olefins with Ethylmagnesium Bromide in the Presence of Titanium Complexes
  作者：U. M. Dzhemilev、V. A. D’yakonov、L. O. Khafizova、A. G. Ibragimov

  DOI：10.1007/s11178-005-0169-z

  日期：2005.3

  Cyclomagnesation of terminal and cyclic olefins and 1,2-dienes with RMgHlg and R2Mg in the presence of dichloro(dicyclopentadienyl)titanium(IV) gives non-Grignard cyclic and acyclic organomagnesium compounds. The reaction direction depends on the structure of unsaturated initial compound. The most probable reaction mechanism is discussed.

  在二氯（二环戊二烯基）钛（IV）存在下，末端和环状烯烃及 1,2-二烯与 RMgHlg 和 R2Mg 发生环镁反应，生成非格氏环状和非环状有机镁化合物。反应方向取决于不饱和初始化合物的结构。讨论了最可能的反应机理。
• Synthesis and transformations of metallacycles
  作者：A. G. Ibragimov、L. O. Khafizova、K. G. Satenov、L. M. Khalilov、L. G. Yakovleva、S. V. Rusakov、U. M. Dzhemilev

  DOI：10.1007/bf02496415

  日期：1999.8

  The Cp2ZrCl2-catalyzed reaction of arylolefins (styrene, o- and p-methylstyrenes, trans-stilbene, 1,4-diphenyl-1,3-butadiene) with AlEt3 resulting in mono- and disubstituted alumacyclopentanes and substituted alumacyclopropanes was studied. The yield and ratio of cyclic organoaluminum compounds depend on the structure of the initial alylolefins and conditions of cycloalumination.
• Catalytic synthesis and transformations of magnesium-cycloalkanes. 1. New catalytic transformations in the series of magnesium-cyclopentanes
  作者：U. M. Dzhemilev、R. M. Sultanov、R. G. Gaimaldinov、G. A. Tolstikov

  DOI：10.1007/bf00961303

  日期：1991.6

  The reactions of magnesium-cyclopentane with styrene and of 2,4-diphenylmagnesium-cyclopentane with ethylene in the presence of catalytic amounts of Cp2ZrCl2 leading to the formation of 2-phenylmagnesium-cyclopentane and 2,4-diphenylmagnesium-cycloheptane, were studied for the first time. It was found that ziroconocyclopentanes, are intermediates in this reaction, which are formed both from magnesium-cycloalkanes and from alpha-olefins and Cp2ZrCl2. A possible mechanism of the reactions studied has been proposed.
• DZHEMILEV, U. M.;SULTANOV, R. M.;GAJMALDINOV, R. G.;TOLSTIKOV, G. A., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1388-1393
  作者：DZHEMILEV, U. M.、SULTANOV, R. M.、GAJMALDINOV, R. G.、TOLSTIKOV, G. A.

  DOI：——

  日期：——