Bis(3-phenylpropyl)(prop-2-EN-1-YL)silane | 391858-36-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(3-phenylpropyl)(prop-2-EN-1-YL)silane
• 英文别名: bis(3-phenylpropyl)-prop-2-enylsilane
• CAS: 391858-36-9
• 化学式: C₂₁H₂₈Si
• 分子量: 308.5
• InChiKey: UMMJXGAZCWKDQF-UHFFFAOYSA-N

物化性质

• 沸点：
  406.8±34.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.67
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  镁 、 1-溴-3-苯基丙烷 、 烯丙基二氯硅烷 、 氯化钠 以 乙醚 为溶剂， 反应 18.33h， 生成 Bis(3-phenylpropyl)(prop-2-EN-1-YL)silane
  参考文献：
  名称：

  Linear chemoselective carbosilane polymers and methods for use in analytical and purification applications

  摘要：

  本发明涉及一类新的化学选择性高的聚合物材料。具体而言，本发明涉及线性聚碳硅烷化合物，用于各种涉及吸附聚合物材料的分析应用，包括色谱、化学捕获、分析物收集和化学传感器应用。这些聚合物具有具有侧链和末端芳基、烷基、烯基和炔基基团，这些基团被卤代醇或酚基团官能化，具有以下一般结构：其中n是大于1的整数；其中R1和R2中至少一个是线性或支链臂，具有至少一个独立于烷基、烯基、炔基和芳基基团或其组合的基团，并且具有至少一个卤代醇或酚基团附着在其上；其中任何所述的R1和R2芳基基团直接或通过短碳氢链连接到所述的[Si-X]n；其中任何剩余的所述R1或R2基团是碳硅烷基团或烃基团；其中X是从烷基、烯基、炔基、芳基基团和其组合中选择的聚合物组分；其中Z1和Z2是独立选择的末端基团，包括烷基、烯基、炔基、芳基、烷基硅烷基、芳基硅烷基、羟基、硅氢化物、烷氧基、卤代醇、卤代酚、有机硅基和其组合。这些聚合物材料主要设计用于吸附氢键碱性分析物，例如有机磷酸酯（神经毒剂和前体）和硝基取代化合物（炸药）。

  公开号：

  US06660230B2

文献信息

• LINEAR CHEMOSELECTIVE CARBOSILANE POLYMERS AND METHODS FOR USE IN ANALYTICAL AND PURIFICATION APPLICATIONS
  申请人：McGill A. Robert

  公开号：US20070003440A1

  公开（公告）日：2007-01-04

  This invention relates generally to a new class of chemoselective polymer materials. In particular, the invention relates to linear polycarbosilane compounds for use in various analytical applications involving sorbent polymer materials, including chromatoghraphy, chemical trapping, analyte collection, and chemical sensor applications. These polymers have pendant and terminal aryl, alkyl, alkenyl, and alkynyl groups that are functionalized with halogen substituted alcohol or phenol groups, having the general structure: wherein n is an integer greater than 1; wherein at least one of R 1 and R 2 is a linear or branched arm having at least one group independently selected from the group consisting of alkyl, alkenyl, alkynyl, and aryl groups, or combinations thereof, and having at least one halogen substituted alcohol or phenol groups attached thereto; wherein any said R 1 and R 2 aryl groups are attached to said [Si—X-] n either directly or through a short hydrocarbon chain; wherein any remaining said R 1 or R 2 group is a hydrocarbon or carbosilane group; wherein X is a polymer component selected from the group consisting of alkylene, alkenylene, alkynylene, arylene groups, and combinations thereof; and wherein Z 1 and Z 2 are end groups independently selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, alkyl silanes, aryl silanes, hydroxyl, silicon hydride, alkoxides, phenols, halogen substituted alcohols, halogen substituted phenols, organosilyl, and combinations thereof. These polymeric materials are primarily designed to sorb hydrogen bond basic analytes such as organophosphonate esters (nerve agents and precursors) and nitro-substituted compounds (explosives).

  本发明涉及一种新型化学选择性聚合物材料。具体而言，本发明涉及线性聚碳硅烷化合物，用于各种涉及吸附聚合物材料的分析应用，包括色谱、化学捕获、分析物收集和化学传感器应用。这些聚合物具有侧链和末端芳基、烷基、烯基和炔基基团，这些基团被卤代醇或酚基团官能化，具有如下通式： 其中n是大于1的整数；其中R1和R2中至少有一个是线性或支链臂，具有至少一个从烷基、烯基、炔基和芳基基团组成的独立选择的群，或这些基团的组合，并且至少有一个卤代醇或酚基团附着在其上；其中任何R1和R2的芳基基团都直接或通过短碳氢链连接到所述[Si—X-]，任何剩余的R1或R2基团是一个碳硅烷基团；其中X是从烷基、烯基、炔基、芳基团组成的聚合物组分，以及这些组分的组合；其中Z1和Z2是独立选择的末端基团，包括烷基、烯基、炔基、芳基、烷基硅烷、芳基硅烷、羟基、硅氢化物、烷氧基、酚基、卤代醇基、卤代酚基、有机硅基团以及这些基团的组合。这些聚合物材料主要设计用于吸附氢键碱性分析物，例如有机磷酸酯（神经毒剂和前体）和硝基取代化合物（爆炸物）。
• Carbosilane polymers and methods for use in analytical and purification applications
  申请人：McGill A. Robert

  公开号：US20070043195A1

  公开（公告）日：2007-02-22

  This invention relates generally to a new class of chemoselective polymer materials. In particular, the invention relates to linear polycarbosilane compounds for use in various analytical applications involving sorbent polymer materials, including chromatography, chemical trapping, analyte collection, and chemical sensor applications. These polymers have pendant and terminal aryl, alkyl, alkenyl, and alkynyl groups that are functionalized with halogen substituted alcohol or phenol groups, having the general structure: wherein n is an integer greater than 1; wherein at least one of R 1 and R 2 is a pendant group having at least one aryl group independently selected from the group consisting of a phenol, a halogen substituted phenol, and an aryl hydrocarbon with a halogen substituted alcohol substitutent, or combinations thereof; wherein any said R 1 and R 2 aryl groups are attached to said [Si—X—] n either directly or through a short hydrocarbon chain; wherein any remaining said R 1 or R 2 group is a hydrocarbon or carbosilane group; wherein X is a polymer component selected from the group consisting of alkylene, alkenylene, alkynylene, arylene groups, and combinations thereof; and wherein Z 1 and Z 2 are end groups independently selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, alkyl silanes, aryl silanes, hydroxyl, silicon hydride, alkoxides, phenols, halogen substituted alcohols, halogen substituted phenols, organosilyl, and combinations thereof. These polymeric materials are primarily designed to sorb hydrogen bond basic analytes such as organophosphonate esters (nerve agents and precursors) and nitro-substituted compounds (explosives).

  本发明涉及一种新型的化学选择性聚合物材料。具体而言，本发明涉及用于各种分析应用的线性聚碳硅烷化合物，这些应用涉及吸附聚合物材料，包括色谱、化学捕获、分析物收集和化学传感器应用。这些聚合物具有侧链和末端芳基、烷基、烯基和炔基基团，这些基团被卤代醇或酚基团官能化，具有以下一般结构： 其中n是大于1的整数；其中R1和R2中至少有一个是侧链基团，具有至少一个芳基，独立地选择自苯酚、卤代苯酚和具有卤代醇取代基的芳基碳氢化合物，或其组合；其中任何所述的R1和R2芳基基团均通过短的碳氢链直接或间接连接到所述[Si—X—]上；其中任何剩余的所述R1或R2基团是烃或碳硅烷基团；其中X是选择自烷基、烯基、炔基、芳基和其组合的聚合物组分；其中Z1和Z2是末端基团，独立地选择自烷基、烯基、炔基、芳基、烷基硅烷、芳基硅烷、羟基、硅氢化物、烷氧基、酚类、卤代醇、卤代苯酚、有机硅基和其组合。这些聚合物材料主要设计用于吸附氢键碱性分析物，如有机磷酸酯（神经毒剂和前体）和硝基取代化合物（爆炸物）。