| 1264885-76-8

• 分子结构分类: 有机化合物
• CAS: 1264885-76-8
• 化学式: C₂₄H₃₇NO₇
• 分子量: 451.56
• InChiKey: HDTOGJIDHMYWPM-IRRSDYHDSA-N

反应信息

• 作为产物：
  描述：

  在 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 1.0h， 以21%的产率得到
  参考文献：
  名称：

  Conversional studies towards taxoids from C₁₉-diterpenoid alkaloids by the BAC sequence

  摘要：

  The conversional synthesis of taxoids by the BAC sequence from the C19-diterpenoid alkaloids, 14-acetyltalatisamine (1), yunaconitine (12), and 14-acetylchasmanine (19), was designed and explored. Two aconane-type diterpenes 17 and 28, the advanced intermediates for our conversional synthesis, were synthesized. The key steps include the rupture of the C(7)-C(17) bond, the formation of imine, and the denitrogenation.

  DOI：

  10.1080/10286020.2010.510796