11-bromododec-1-ene | 838821-64-0

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 11-bromododec-1-ene
• CAS: 838821-64-0
• 化学式: C₁₂H₂₃Br
• 分子量: 247.219
• InChiKey: JBNIGAHHUFPRBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trichloro-(4-methoxyphenyl)stannane 、 11-bromododec-1-ene 在 2,2'-联吡啶 、 potassium tert-butylate 、 nickel dichloride 作用下， 以 异丁醇 、 叔丁醇 为溶剂， 反应 12.0h， 以70%的产率得到1-metoxy-4-(1-methylundec-10-enyl)benzene
  参考文献：
  名称：

  Stille Cross-Couplings of Unactivated Secondary Alkyl Halides Using Monoorganotin Reagents

  摘要：

  The first catalyst that achieves Stille cross-couplings of secondary (as well as primary) alkyl halides has been developed. The method employs easily handled and inexpensive catalyst components (NiCl2 and 2,2'-bipyridine) and, through the use of monoorganotin reagents, avoids the formation of toxic and difficult-to-remove triorganotin side products.

  DOI：

  10.1021/ja0436300
• 作为产物：
  描述：

  10-十一烯醛 在 溴 、 三苯基膦 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 15.0h， 生成 11-bromododec-1-ene
  参考文献：
  名称：

  Stille Cross-Couplings of Unactivated Secondary Alkyl Halides Using Monoorganotin Reagents

  摘要：

  The first catalyst that achieves Stille cross-couplings of secondary (as well as primary) alkyl halides has been developed. The method employs easily handled and inexpensive catalyst components (NiCl2 and 2,2'-bipyridine) and, through the use of monoorganotin reagents, avoids the formation of toxic and difficult-to-remove triorganotin side products.

  DOI：

  10.1021/ja0436300

文献信息

• ELECTRONIC DEVICE USING ORGANIC THIN FILM, AND ELECTRONIC APPARATUS CONTAINING SAME
  申请人：Japan Science and Technology Agency

  公开号：EP2958148A1

  公开（公告）日：2015-12-23

  The present invention provides a high-performance, highly homogeneous, highly stable electronic device by forming an extremely uniform interface between an insulator and an organic semiconductor, as well as an electronic apparatus using the same. The present invention relates to an electronic device which contains, as a component, an organic thin film in which a geometric two-dimensional arrangement is formed regularly by interdigitating skeletal structures of a positive three-pronged shape of triptycene and by adding a first molecule extending out of one plane of a two-dimensional molecular structure of the triptycene skeletal structure. The invention also relates to an electronic apparatus and the like which contains the electronic device in the interior of the electronic apparatus.

  本发明通过在绝缘体和有机半导体之间形成极其均匀的界面，提供了一种高性能、高均匀性、高稳定性的电子器件，以及使用这种器件的电子设备。本发明涉及一种电子器件，它包含一种有机薄膜，在该薄膜中，三庚烯的正三棱形骨架结构相互交错，并加入从三庚烯骨架结构的二维分子结构的一个平面延伸出来的第一分子，从而有规律地形成几何二维排列。本发明还涉及一种电子设备和类似设备，它在电子设备的内部装有电子装置。
• Mixed dimers from alpha-olefin sulfonic acids
  申请人：STEPAN COMPANY

  公开号：US10590331B2

  公开（公告）日：2020-03-17

  Mixed dimer and mixed oligomer compositions are disclosed. The mixed dimer compositions comprise a monosulfonated cross-dimer or a salt thereof. The monosulfonated cross-dimer is a reaction product of (a) an alpha-olefin sulfonic acid (AOS acid); and (b) an unsulfonated olefin, an unsulfonated olefin precursor, or a functionalized olefin. The mixed oligomer compositions comprise a mono- or polysulfonated cross-oligomer or a salt thereof. The mono- or polysulfonated cross-oligomer is a reaction product of (a) an AOS acid; and (b) an unsulfonated diolefin or an unsulfonated diolefin precursor. Various methods for making the mixed dimer or oligomer compositions are described. Salts of the mixed dimer and oligomer compositions are useful surfactants for foams used in oilfield and other applications. The foams have improved high-temperature stability when compared with foams from AOS dimer acid salts.

  本发明公开了混合二聚体和混合低聚物组合物。混合二聚体组合物包括单磺化交联二聚体或其盐。单磺化交联二聚体是 (a) α-烯烃磺酸（AOS 酸）；和 (b) 未磺化烯烃、未磺化烯烃前体或官能化烯烃的反应产物。混合低聚物组合物包括单磺化或多磺化交叉低聚物或其盐。单磺化或多磺化交叉低聚物是 (a) AOS 酸和 (b) 未磺化二烯烃或未磺化二烯烃前体的反应产物。本文介绍了制造混合二聚体或低聚物组合物的各种方法。混合二聚体和低聚物组合物的盐类是用于油田和其他应用中的泡沫的有用表面活性剂。与来自 AOS 二聚酸盐类的泡沫相比，这些泡沫具有更好的高温稳定性。
• Method for treating surface of resin material layer and resin material
  申请人：MITSUBISHI HEAVY INDUSTRIES, LTD.

  公开号：US11111348B2

  公开（公告）日：2021-09-07

  A method is for treating a surface of a resin material layer. The method includes a first step of introducing as a substituent at least one selected from the group consisting of an acid halide and an alkyl halide into an aromatic polyether-based resin included in the resin material layer by Friedel-Crafts reaction.

  一种处理树脂材料层表面的方法。该方法包括第一步，通过 Friedel-Crafts 反应，将至少一种选自酸卤化物和烷基卤化物的取代基引入树脂材料层中的芳香族聚醚基树脂。
• MIXED DIMERS FROM ALPHA-OLEFIN SULFONIC ACIDS
  申请人：Stepan Company

  公开号：EP3331963B1

  公开（公告）日：2019-07-10
• METHOD FOR TREATING SURFACE OF RESIN MATERIAL LAYER AND RESIN MATERIAL
  申请人：Mitsubishi Heavy Industries, Ltd.

  公开号：EP3450488B1

  公开（公告）日：2021-03-24