2-benzoylbenzenemethanol | 100560-58-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-benzoylbenzenemethanol
• 英文别名: methylolbenzophenone；o-Idrossimetilbenzofenone；[2-(Hydroxymethyl)phenyl](phenyl)methanone；[2-(hydroxymethyl)phenyl]-phenylmethanone
• CAS: 100560-58-5
• 化学式: C₁₄H₁₂O₂
• 分子量: 212.248
• InChiKey: LQMCLODQWWUWLH-UHFFFAOYSA-N

物化性质

• 沸点：
  411.6±28.0 °C(Predicted)
• 密度：
  1.170±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-benzoylbenzenemethanol 、 对甲苯磺酰肼 在 盐酸 作用下， 以 甲醇 为溶剂， 反应 10.0h， 以46%的产率得到2-(hydroxymethyl)benzophenone tosylhydrazone
  参考文献：
  名称：

  Carbenes and the oxygen-hydrogen bond: hydroxyalkyl-substituted arylcarbenes

  摘要：

  DOI：

  10.1021/jo00295a018
• 作为产物：
  描述：

  1-amino-1,3-dihydro-1-phenylisobenzofuran 在 Dowex 50 W-X₈ 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 11.0h， 生成 2-benzoylbenzenemethanol
  参考文献：
  名称：

  1-Phenylisobenzofuran, 1-phenylnaphtho[2,3-c]furan, 1-phenylnaphtho[1,2-c]furan, and 3-phenylnaphtho[1,2-c]furan via cyclic hemiaminal, hemiacetal, and acetal precursors

  摘要：

  DOI：

  10.1021/jo00248a009

文献信息

• IONIC LIQUID SYSTEMS
  申请人：The Procter & Gamble Company

  公开号：US20160177222A1

  公开（公告）日：2016-06-23

  The present invention relates to an ionic liquid system for enhanced delivery and/or deposition of a perfume raw material onto a substrate, particularly fabric, hard surfaces, soft surfaces, skin, or hair. The invention also relates to consumer products comprising the new ionic liquid systems, and processes for making and methods of using such ionic liquid systems and consumer products.

  本发明涉及一种离子液体系统，用于增强香水原料在基底上的传递和/或沉积，特别是织物、硬表面、软表面、皮肤或头发。该发明还涉及包含新离子液体系统的消费产品，以及制造和使用这种离子液体系统和消费产品的方法。
• [EN] CHEMICAL AGENTS CAPABLE OF FORMING COVALENT 3-D NETWORKS<br/>[FR] AGENTS CHIMIQUES APTES À FORMER DES RÉSEAUX TRIDIMENSIONNELS COVALENTS
  申请人：OXFORD ADVANCED SURFACES LTD

  公开号：WO2010100410A1

  公开（公告）日：2010-09-10

  The invention provides a functionalised compound of formula (II), which functionalised compound comprises n carbene precursor groups which are the same or different, wherein n is an integer equal to or greater than 3: wherein x is 1, E is a group which is capable of being converted into a carbene reactive intermediate group, Q is a core moiety, a polymer or a dendrimer, and each of the [R]x-E-L- groups, which are the same or different, is independently selected from a group of formula (Ie) and a group of formula (Ia): wherein L is a single bond or a linker group as defined herein, R is a terminal group as defined herein, and R1 is as defined herein. Further provided is the use of the functionalised compound as an agent for producing a chemically-bound three-dimensional network on or within a substrate. Processes for producing the following products using the functionalised compounds of the invention are also provided, as are the resulting products: a chemically- bound three-dimensional network on or within a substrate; a chemically-bound three- dimensional network between a first substrate and a second substrate; a film or a coating; a coated substrate; a product which comprises a first substrate, a second substrate and a composition at an interface of the first and second substrates; a treated particle. The invention further provides a process for cross linking a first substrate to a second substrate, using a functionalised compound of the invention, and the resulting cross-linked product. The invention also provides a process for producing the functionalised compounds of the invention.

  本发明提供了一种式子为(II)的功能化化合物，该功能化化合物包括n个相同或不同的卡宾前体基团，其中n是大于或等于3的整数：其中x为1，E为能转化为卡宾反应中间体基团的基团，Q为核心基团、聚合物或树状分子，而每个[R]x-E-L-基团，相同或不同，独立地选择自式(Ie)和式(Ia)的基团：其中L为单键或如此定义的连接基团，R为如此定义的末端基团，而R1如此定义。本发明还提供了将功能化化合物用作在基质上或内部产生化学结合的三维网络的制剂。本发明还提供了使用本发明的功能化化合物制备以下产品的方法，以及相应的产品：在基质上或内部的化学结合三维网络；第一基质和第二基质之间的化学结合三维网络；薄膜或涂层；涂层基质；包括第一基质、第二基质和位于第一基质和第二基质界面处的组成物的产品；处理过的粒子。本发明还提供了一种使用本发明的功能化化合物交联第一基质和第二基质的方法以及所得到的交联产品。本发明还提供了制备本发明的功能化化合物的方法。
• CHEMICAL AGENTS CAPABLE OF FORMING COVALENT 3-D NETWORKS
  申请人：Griffiths Jon-Paul

  公开号：US20120021223A1

  公开（公告）日：2012-01-26

  The invention provides a functionalised compound of formula (II), which functionalised compound comprises n carbene precursor groups which are the same or different, wherein n is an integer equal to or greater than 3: wherein x is 1, E is a group which is capable of being converted into a carbene reactive intermediate group, Q is a core moiety, a polymer or a dendrimer, and each of the [R] x -E-L- groups, which are the same or different, is independently selected from a group of formula (Ie) and a group of formula (Ia): wherein L is a single bond or a linker group as defined herein, R is a terminal group as defined herein, and R 1 is as defined herein. Further provided is the use of the functionalised compound as an agent for producing a chemically-bound three-dimensional network on or within a substrate. Processes for producing the following products using the functionalised compounds of the invention are also provided, as are the resulting products: a chemically-bound three-dimensional network on or within a substrate; a chemically-bound three-dimensional network between a first substrate and a second substrate; a film or a coating; a coated substrate; a product which comprises a first substrate, a second substrate and a composition at an interface of the first and second substrates; a treated particle. The invention further provides a process for cross linking a first substrate to a second substrate, using a functionalised compound of the invention, and the resulting cross-linked product. The invention also provides a process for producing the functionalised compounds of the invention.

  本发明提供了一个式子为(II)的官能化合物，该官能化合物包括n个卡宾前体基团，这些基团相同或不同，其中n是大于或等于3的整数：其中x为1，E为能够转化为卡宾反应中间体基团的基团，Q为核心基团、聚合物或树状分子，每个[R]x-E-L-基团（相同或不同）独立地选择自公式(Ie)和公式(Ia)的基团，其中L为单键或如下所定义的连接基团，R为如下所定义的末端基团，R1如下所定义。本发明还提供了利用官能化合物作为在基底上或内部产生化学结合三维网络的试剂。本发明还提供了使用本发明的官能化合物制备以下产品的过程，以及所得到的产品：在基底上或内部产生化学结合三维网络；第一基底和第二基底之间的化学结合三维网络；薄膜或涂层；涂层基底；包括第一基底、第二基底和位于第一和第二基底界面处的组成物的产品；处理过的颗粒。本发明还提供了使用本发明的官能化合物交联第一基底和第二基底的过程以及所得到的交联产品。本发明还提供了制备本发明的官能化合物的过程。
• A process for the preparation of a benzhydrol derivative and a novel intermediate for use therein
  申请人：Farmos-Yhtyma Oy

  公开号：EP0033585A1

  公开（公告）日：1981-08-12

  2-[N-(2-hydroxyethyl)-N-methyl]-amino}-methylbenz- hydrol, which is used as an intermediate when producing 3,4,5,6-tetrahydro-5-methyl-1-phenyl-1 H-2,5-benz- oxazocine-hydrochloride or nefopam, which is used as a muscle relaxant, an analgesic or antidepressive drug, is advantageously made by reacting 2-chloromethylbenzophenone with methylethanolamine, and reducing the thus produced 2-[N-(2-hydroxyethyl)-N-methyl]-amino}- methylbenzophenone with sodium borohydride.

  2-[N-(2-羟乙基)-N-甲基]-氨基}-甲基二苯甲酰基，在生产 3,4,5,6-四氢-5-甲基-1-苯基-1 H-2,5-苯噁唑嗪盐酸盐或用作肌肉松弛剂的奈福泮时用作中间体、2-[N-(2-hydroxyethyl)-N-methyl]-amino}- methylbenzophenone 与甲基乙醇胺反应，并用硼氢化钠还原生成 2-[N-(2-羟乙基)-N-甲基]-氨基}-甲基二苯甲酮。
• Vernetzbare Exlastomerzusammensetzungen, Verfahren zu deren Herstellung und deren Verwendung
  申请人：LANXESS Deutschland GmbH

  公开号：EP1770119A1

  公开（公告）日：2007-04-04

  Bereitgestellt werden neue vernetzbare Zusammensetzungen auf der Basis von Elastomeren, von denen mindestens eines Carboxyl- und/oder Carboxylat-Gruppen aufweist, wobei diese vernetzbaren Zusammensetzungen spezielle ungesättigte organische Salze von Metallionen sowie ein Vernetzungssystem enthalten, welches als Radikalspender fungiert. Daraus erhältlich sind vernetzte Elastomere, die über ausgezeichnete physikalische Eigenschaften verfügen. Die neuen vernetzbaren Zusammensetzungen lassen sich vielfältig einsetzen.

  提供了基于弹性体的新型可交联组合物，其中至少一种弹性体具有羧基和/或羧酸基，这些可交联组合物含有金属离子的特殊不饱和有机盐和作为自由基供体的交联体系。因此，交联弹性体具有优异的物理特性。新型可交联组合物的应用范围非常广泛。