(diphenylphosphinoethane)PtH(CN) | 122707-22-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (diphenylphosphinoethane)PtH(CN)
• CAS: 122707-22-6
• 化学式: C₂₇H₂₅NP₂Pt
• 分子量: 620.53
• InChiKey: VFJCZZCYVZSNEQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(diphenylphosphinoethane)PtH]2 、 苯甲腈 以 苯甲腈 为溶剂， 以40%的产率得到(diphenylphosphinoethane)PtH(CN)
  参考文献：
  名称：

  C−CN vs C−H Cleavage of Benzonitrile Using [(dippe)PtH]₂

  摘要：

  The reaction of [(dippe)PtH](2) with benzonitrile at 140 degrees C produced two products, the C-H-activated adduct (dippe)Pt(H)(2-C6H4CN) (2) and the C-CN-activated adduct (dippe)Pt(Ph)(CN) (5), with the kinetically favored C-H activation product forming in a significant majority (similar to 18:1). Further reaction showed a formal beta-cyano elimination in 2, forming (dippe)Pt(H)(CN) (3) and benzene. Following the elimination, C-H activation of a second benzonitrile by 3 led to three regioisomers of (dippe)Pt(CN)(C6H4CN) (4).

  DOI：

  10.1021/om101069j