(2Z,8E)-deca-2,8-diene-1,10-diol | 1402693-07-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (2Z,8E)-deca-2,8-diene-1,10-diol
• CAS: 1402693-07-5
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: DGSFTVDRMYHDEH-CGXWXWIYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (2Z,8E)-dimethyl deca-2,8-dienedioate 在 二异丁基氢化铝 作用下， 以 二氯甲烷 为溶剂， 反应 0.83h， 以92%的产率得到(2Z,8E)-deca-2,8-diene-1,10-diol
  参考文献：
  名称：

  One-Pot Oxidation/Isomerization of Z-Allylic Alcohols with Oxygen as Stoichiometric Oxidant

  摘要：

  A method for generating (E)-alpha,beta-unsaturated aldehydes from Z-allylic alcohols or E/Z-mixtures is described. The one-pot procedure involves a Cu-catalyzed oxidation followed by an organocatalytic DE-isomerization with N,N-dimethylaminopyridine (DMAP).

  DOI：

  10.1021/ol302420k

文献信息

• MULTIFUNCTIONAL MONOMERS, METHODS FOR MAKING MULTIFUNCTIONAL MONOMERS, POLYMERIZABLE COMPOSTIONS AND PRODUCTS FORMED THEREFORM
  申请人：Bioformix Inc.

  公开号：US20140329980A1

  公开（公告）日：2014-11-06

  The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
• US9512058B2
  申请人：——

  公开号：US9512058B2

  公开（公告）日：2016-12-06