1-fluoro-4-(vinyloxymethyl)benzene | 1351397-18-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-fluoro-4-(vinyloxymethyl)benzene
• 英文别名: 1-(Ethenoxymethyl)-4-fluorobenzene；1-(ethenoxymethyl)-4-fluorobenzene
• CAS: 1351397-18-6
• 化学式: C₉H₉FO
• 分子量: 152.168
• InChiKey: BBMXNOISXHLMAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-fluoro-4-(vinyloxymethyl)benzene 、 1,4-萘醌 在 silver(I) acetate 、 palladium diacetate 作用下， 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以62%的产率得到2-((4-fluorobenzyl)oxy)anthracene-9,10-dione
  参考文献：
  名称：

  钯催化的烯烃直接交叉偶联取代苯环的构建：快速合成1,4-萘醌及其衍生物的途径

  摘要：

  应对变化：缺电子的1,4-苯醌或其衍生物与富电子的烷基乙烯基醚的直接交叉偶联以串联方式进行，以产生具有良好选择性和良好至极佳收率的取代苯环（请参见方案） ）。该反应具有快速合成各种取代的苯环的潜力，因为它不受取代基作用的限制。

  DOI：

  10.1002/anie.201103380
• 作为产物：
  描述：

  对氟苯甲醇 、 乙烯基正丁醚 在 palladium(II) trifluoroacetate 、 三乙胺 作用下， 反应 16.0h， 以67%的产率得到1-fluoro-4-(vinyloxymethyl)benzene
  参考文献：
  名称：

  钯催化的烯烃直接交叉偶联取代苯环的构建：快速合成1,4-萘醌及其衍生物的途径

  摘要：

  应对变化：缺电子的1,4-苯醌或其衍生物与富电子的烷基乙烯基醚的直接交叉偶联以串联方式进行，以产生具有良好选择性和良好至极佳收率的取代苯环（请参见方案） ）。该反应具有快速合成各种取代的苯环的潜力，因为它不受取代基作用的限制。

  DOI：

  10.1002/anie.201103380

文献信息

• ABA TRIBLOCK COPOLYMER AND PROCESS FOR PRODUCING THE SAME
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：EP2186837A1

  公开（公告）日：2010-05-19

  To provide a novel ABA-type triblock copolymer of vinyl ether series, comprising polyvinyl ether and an oxystyrene-series unit, and a process of producing the ABA-type copolymer at a series of steps. The invention relates to a novel ABA-type triblock copolymer comprising Segment A comprising an oxystyrene-series repeat unit (a) and Segment B comprising a vinyl ether-series repeat unit (b), in which the Segment A and the Segment B are bonded together with a single bond, and to a simple process of producing the same. The triblock copolymer can be produced at a series of steps in a simple manner, comprising living cationic polymerization of a vinyl ether-series monomer such as ethyl vinyl ether in the presence of a bifunctional initiator and a Lewis acid, and subsequently adding an oxystyrene-series monomer such as p-hydroxystyrene for living cationic polymerization.

  提供一种新型 ABA 型乙烯基醚系列三嵌段共聚物，该共聚物由聚乙烯醚和氧苯乙烯系列单元组成，并提供一种通过一系列步骤生产该 ABA 型共聚物的工艺。本发明涉及一种新颖的 ABA 型三嵌段共聚物，它由包含氧苯乙烯系列重复单元 （a）的段 A 和包含乙烯基醚系列重复单元（b）的段 B 组成，其中段 A 和段 B 以单 键结合在一起，本发明还涉及生产这种共聚物的简单工艺。三嵌段共聚物可以通过一系列简单步骤生产，包括在双官能团引发剂和路易斯酸存在下，乙烯基醚系列单体（如乙基乙烯基醚）的活阳离子聚合，然后加入氧基苯乙烯系列单体（如对羟基苯乙烯）进行活阳离子聚合。
• VINYL ETHER-BASED STAR POLYMER AND PROCESS FOR PRODUCTION THEREOF
  申请人：Maruzen Petrochemical CO., LTD.

  公开号：EP2412737A1

  公开（公告）日：2012-02-01

  Provided is a vinyl ether-based star polymer which has an arm including a vinyl ether polymer and an arm including an oxystyrene polymer. Also provided is a process for producing the star polymer, which can be continuously carried out in a series of steps. Said vinyl ether-based star polymer and process for producing the same are such that the polymer includes a core and polymer-chain arm portions extending from the core, in which an arm portion including vinyl ether repeating units and an arm portion including oxystyrene repeating units are provided.

  本发明提供了一种乙烯基醚基星形聚合物，其臂部包括乙烯基醚聚合物，臂部包括氧苯乙烯聚合物。此外，还提供了一种生产该星型聚合物的工艺，该工艺可通过一系列步骤连续进行。所述乙烯基醚基星形聚合物及其生产工艺使该聚合物包括一个核心和从核心延伸出来的聚合物链臂部分，其中臂部分包括乙烯基醚重复单元和臂部分包括氧苯乙烯重复单元。
• Method for producing polymer for electronic material and polymer for electronic material obtained by the production method
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US10766973B2

  公开（公告）日：2020-09-08

  Provided is a method for producing a polymer for an electronic material having a low content of metal ion impurities and a polymer for an electronic material obtained by such method. The method for producing a polymer for an electronic material according to the present invention comprises a polymerization step of obtaining a polymer by polymerizing a monomer(s) and a purification step of adding a strong acid having 0 or less pKa to the polymer solution and subsequently performing an ion exchange treatment to reduce the concentration of the metal ion impurities.

  本发明提供了一种生产金属离子杂质含量低的电子材料用聚合物的方法，以及通过该方法获得的电子材料用聚合物。 根据本发明，生产电子材料用聚合物的方法包括：通过聚合单体获得聚合物的聚合步骤；向聚合物溶液中添加 pKa 值为 0 或更小的强酸并随后进行离子交换处理以降低金属离子杂质浓度的净化步骤。
• METHOD FOR PRODUCING POLYMER FOR ELECTRONIC MATERIAL AND POLYMER FOR ELECTRONIC MATERIAL OBTAINED BY THE PRODUCTION METHOD
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20180134819A1

  公开（公告）日：2018-05-17

  Provided is a method for producing a polymer for an electronic material having a low content of metal ion impurities and a polymer for an electronic material obtained by such method. The method for producing a polymer for an electronic material according to the present invention comprises a polymerization step of obtaining a polymer by polymerizing a monomer(s) and a purification step of adding a strong acid having 0 or less pKa to the polymer solution and subsequently performing an ion exchange treatment to reduce the concentration of the metal ion impurities.
• SILOXANE MONOMER, POLYMER THEREOF, COMPOSITION CONTAINING SAID POLYMER, AND ELECTRONIC ELEMENT
  申请人：DIC Corporation

  公开号：US20180223181A1

  公开（公告）日：2018-08-09

  An object of the present invention is to provide a polymer obtained from novel monomers, a composition containing the polymer, an electronic material composition, and an electronic element, the polymer, by being added to the electronic material composition or ink applied for coating film formation, improving the smoothness (leveling property) of a coating film to be obtained without deteriorating a driving stability of the electronic element. With the novel siloxane monomers, the polymer thereof, the composition containing the polymer, and the electronic material composition according to the present invention, it is possible to produce a smooth organic thin film. The electronic element including either of these compositions has a prolonged element lifetime and improved driving stability.