1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-1,8-bis(1,2,2-trifluoroethenoxy)octane | 1173181-85-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-1,8-bis(1,2,2-trifluoroethenoxy)octane
• CAS: 1173181-85-5
• 化学式: C₁₂F₂₂O₂
• 分子量: 594.096
• InChiKey: BKINOWQLXSJGBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  36
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  24

反应信息

• 作为产物：
  描述：

  CF2Cl-CFCl-O-(CF2)8-O-CFCl-CF2Cl 在 锌 作用下， 以 异丙醇 为溶剂， 以73%的产率得到1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Hexadecafluoro-1,8-bis(1,2,2-trifluoroethenoxy)octane
  参考文献：
  名称：

  Coupling Reactions of Chlorofluoro and Perfluoroalkyl Iodides

  摘要：

  氯氟烷基碘化物Rf-I与Rf = ClCF2CFCl（CF2）3CF2-，ClCF2CFClO（CF2）3CF2-，ClCF2CFCl-，（CF3）2CF-，（CF3）2CFCF2CF2-在锌/溶剂体系存在下进行偶联反应，产生良好收率的二聚体。研究了同聚反应（一个碘化物）和异聚反应（两个不同的碘化物）。显示了温度和溶剂的影响。二聚体中邻位氯原子的锌介导脱氯反应产生了末端烯烃和二烯烃。

  DOI：

  10.1135/cccc20081719

文献信息

• NOVEL CROSSLINKABLE FLUORINE-CONTAINING ETHER COMPOUND
  申请人：ITO Takayuki

  公开号：US20080255337A1

  公开（公告）日：2008-10-16

  A crosslinkable fluorine-containing compound, which is an adduct compound having a crosslinkable group, wherein the adduct compound is an adduct of a fluorine-containing compound having, per molecule, 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom.
• NOVEL FLUORINE-CONTAINING POLYMER AND METHOD OF PRODUCING FLUORINE-CONTAINING POLYMER
  申请人：Ito Takayuki

  公开号：US20090318650A1

  公开（公告）日：2009-12-24

  A method of producing a fluorine-containing polymer, containing conducting an addition polymerization of a fluorine-containing compound having 2 or more terminal fluorine-containing vinyl groups each directly bonded to an oxygen atom per molecule, and a compound having 2 or more groups represented by —XH, where X represents an oxygen atom or a sulfur atom; and a fluorine-containing polymer comprising a repeating unit represented by formula (i): wherein Rf 1 represents a perfluoroalkylene group; each of Rf 2 and Rf 3 independently represents a fluorine atom, a perfluoroalkyl group or a perfluoroalkoxy group; at least two among Rf 1 , Rf 2 and Rf 3 may bond to each other to form a ring structure; X represents an oxygen atom or a sulfur atom; and L represents a divalent organic group.
• US8119765B2
  申请人：——

  公开号：US8119765B2

  公开（公告）日：2012-02-21
• US8236923B2
  申请人：——

  公开号：US8236923B2

  公开（公告）日：2012-08-07