cobalt(II) 5,15-di(o-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butylporphyrin | 680583-57-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: cobalt(II) 5,15-di(o-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butylporphyrin
• CAS: 680583-57-7
• 化学式: C₅₄H₆₄CoN₄O₂
• 分子量: 860.121
• InChiKey: KDMQJYRXNBIXNI-HQYFUODISA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) acetate 、 5,15-(ortho-methyloxyphenyl)-2,8,12,18-tetramethyl-3,7,13,17-tetrabutylporphyrin 以 乙醇 、 苯 为溶剂， 生成 cobalt(II) 5,15-di(o-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butylporphyrin
  参考文献：
  名称：

  Coordinating Properties of Co(II) and Zn(II) Complexes with Sterically Hindered Porphyrins

  摘要：

  Cobalt(II) and zinc(II) complexes with 5,15-di(o-methoxyphenyl)-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-buthylpotphyrin and its capped analogues, where the MN4 reaction site is shielded by bridging a groups containing m-phenylene and dimethoxy-substituted p-phenylene fragments, were synthesized. Equilibrium constants of additional coordination of pyridine and N-methylimidazole by these metalloporphyrins were determined at 298 K. It was found that steric distortion of the porphyrin core destabilizes extra complexes.

  DOI：

  10.1023/b:ruco.0000003438.29891.24