silver;cyclopenta-2,4-dien-1-yl-diphenyl-selanylidene-λ5-phosphane;iron(2+);2-pyridin-2-ylpyridine;trifluoromethanesulfonate | 327186-50-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: silver;cyclopenta-2,4-dien-1-yl-diphenyl-selanylidene-λ5-phosphane;iron(2+);2-pyridin-2-ylpyridine;trifluoromethanesulfonate
• CAS: 327186-50-5
• 化学式: CF₃O₃S*C₄₄H₃₆AgFeN₂P₂Se₂
• 分子量: 1125.44
• InChiKey: KMVBBKOGXLWPEN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.76
• 重原子数：
  60
• 可旋转键数：
  7
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  91.4
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 silver;cyclopenta-2,4-dien-1-yl-diphenyl-selanylidene-λ5-phosphane;iron(2+);trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以64%的产率得到silver;cyclopenta-2,4-dien-1-yl-diphenyl-selanylidene-λ5-phosphane;iron(2+);2-pyridin-2-ylpyridine;trifluoromethanesulfonate
  参考文献：
  名称：

  Coordination chemistry of 1,1′-bis(diphenylselenophosphoryl)ferrocene (dpspf) towards Group 11 elements. Crystal structures of [Ag(dpspf){(SPPh2)2CH2}]OTf and [Au(dpspf)][AuCl2]

  摘要：

  The ligand 1,1'-bis(diphenylselenophosphoryl)ferrocene, dpspf, reacted with various Group 11 derivatives to afford the complexes[M(dpspf)]X (M = Cu, Ag, Au; X = OTf, C10 (4), [AuCl2). The crystal structure of [Au(dpspf][AuCl2] revealed a trans coordination of the dpspf ligand and the presence of short Au-Au interactions in the cation. The complex [Ag(dpspf)]OTf can react further with bidentate ligands to give the four-coordinate complexes [M(dpspf)(L-L)]OTf (L-L=(SPPh2)(2)CH2, (SePPh2)(2)CH2, 2,2'-bipyridine or dpspf). The structure of the derivative with L-L=(SPPh2)(2)CH2 was confirmed by X-ray diffraction. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00465-4