tridecafluorodecyl 4-methylbenzenesulfonate | 134440-52-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tridecafluorodecyl 4-methylbenzenesulfonate
• 英文别名: 5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluorodecyl 4-methylbenzenesulfonate
• CAS: 134440-52-1
• 化学式: C₁₇H₁₅F₁₃O₃S
• 分子量: 546.35
• InChiKey: GNBOHWFGDJFZGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.61
• 重原子数：
  34.0
• 可旋转键数：
  11.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  tridecafluorodecyl 4-methylbenzenesulfonate 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 22.0h， 生成 perfluorohexylbutanethiol
  参考文献：
  名称：

  Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer

  摘要：

  New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) containing a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity higher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00303-8
• 作为产物：
  描述：

  Diethyl tridecylfluoro-octyl-malonat 在 氢氧化钾 、 lithium aluminium tetrahydride 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 16.0h， 生成 tridecafluorodecyl 4-methylbenzenesulfonate
  参考文献：
  名称：

  Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer

  摘要：

  New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) containing a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity higher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)00303-8

文献信息

• Selective Synthesis of Single- and Multi-Walled Supramolecular Nanotubes by Using Solvophobic/Solvophilic Controls: Stepwise Radial Growth via “Coil-on-Tube” Intermediates
  作者：Seelam Prasanthkumar、Wei Zhang、Wusong Jin、Takanori Fukushima、Takuzo Aida

  DOI：10.1002/anie.201505806

  日期：2015.9.14

  solvated in C6F6 (solvophilic effect) and do not assemble, whereas in CH2Cl2, they are excluded (solvophobic effect) and assemble together consequently. For example, the use of C6F6 and CH2Cl2 as assembling media for FHBC leads to the selective formation of single‐ and multi‐walled nanotubes, respectively. When a higher monomer concentration is applied in CH2Cl2, multi‐walled nanotubes with a larger number

  新颖六围-hexabenzocoronene（HBC）衍生物，˚F HBC和˚F HBC *，这进行HBC芯和在另一长链烷基的尾部的一侧全氟烷片段，合成的。它们的全氟烷基链段在C 6 F 6中高度溶剂化（亲溶剂作用）并且不组装，而在CH 2 Cl 2中，它们被排除（疏溶剂作用）并因此组装在一起。例如，使用C 6 F 6和CH 2 Cl 2作为F的组装介质HBC分别选择性地形成了单壁和多壁纳米管。当在CH 2 Cl 2中使用较高的单体浓度时，会产生壁数较大的多壁纳米管。CH 2 Cl 2中的F HBC自组装相当缓慢，因此可以观察线圈上的结构，这可能是纳米管壁逐步放射状生长的中间产物。将多壁纳米管浇铸到石英板上会产生超疏水薄膜，水接触角为161±2°。