9,11,11,11-tetrachloroundecyl acetate | 13038-49-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 9,11,11,11-tetrachloroundecyl acetate
• 英文别名: 1-Acetoxy-9,11,11,11-tetrachlorundecan
• CAS: 13038-49-8
• 化学式: C₁₃H₂₂Cl₄O₂
• 分子量: 352.128
• InChiKey: PXXTXHOBPJBARE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  四氯化碳 、 10-乙酰-1-癸 在 过氧化苯甲酰 作用下， 生成 9,11,11,11-tetrachloroundecyl acetate
  参考文献：
  名称：

  Dolezal,S., Collection of Czechoslovak Chemical Communications, 1966, vol. 31, p. 3765 - 3774

  摘要：

  DOI：

文献信息

• Addition Reaction of Polychloro Compounds to Carbon-Carbon Multiple Bonds Catalyzed by Semiconductor Particles under Photoirradiation
  作者：Michiharu Mitani、Takuya Kiriyama、Tomoaki Kuratate

  DOI：10.1021/jo00085a013

  日期：1994.3

  Polychloro compounds were added to olefins in the presence of semiconductor particles (TiO2 or CdS) under photoirradiation. The photoreaction without semiconductors afforded no adducts at all; however, loading of TiO2 with Ag, Cu, or Fe3O4 enhanced the yield of the photoaddition reaction even further. Semiconductors operate as catalysts for the one-electron injection into the polychloro compounds. The relative adsorptions of the polychloro compounds onto the semiconductor particles correlate with the yields of the adducts, while the half-wave reduction potentials of the polychlorides do not. This semiconductor-catalyzed reaction was selective to unfunctionalized olefins and to those bearing a functional group at a remote position. An alkyne furnished the product via further reduction following addition, i.e., 1,1,3-trichloro-1-heptene (7) from 1-hexyne and carbon tetrachloride.