4-((3,5-di-tert-butylphenyl)-(4-(trimethylsilyl)phenyl)amino)benzaldehyde | 1447918-02-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-((3,5-di-tert-butylphenyl)-(4-(trimethylsilyl)phenyl)amino)benzaldehyde
• CAS: 1447918-02-6
• 化学式: C₃₀H₃₉NOSi
• 分子量: 457.731
• InChiKey: RRIOFJKMQAVSLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.11
• 重原子数：
  33.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  20.31
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (6,8-di-tert-butyl-2-methyl-4H-chromen-4-ylidene)malononitrile 、 4-((3,5-di-tert-butylphenyl)-(4-(trimethylsilyl)phenyl)amino)benzaldehyde 在 哌啶 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以78%的产率得到2-(6,8-di-tert-butyl-2-(4-((3,5-di-tertbutylphenyl)(4-(trimethylsilyl)phenyl)amino)styryl)-4H-chromen-4-ylidene)malononitrile
  参考文献：
  名称：

  Synthesis and Electroluminescent Properties of Red Fluorescent 2-(6,8-di-tert-butyl-2-(4-((3,5-di-tert-butylphenyl)(4-(trimethylsilyl)phenyl)amino)styryl)-4H-chromen-4-ylidene)malononitrile (DCCTBPA) for Organic Light-Emitting Diodes (OLEDs)

  摘要：

  We synthesize a red fluorescent material, 2-(6,8-di-tert-butyl-2-(4-((3,5-di-tert-butylphenyl)(4-(trimethylsilyl)phenyl)amino)styryl)-4H-chromen-4-ylidene)malononitrile (DCCTBPA) using Knoevenagel condensation. To explore the electroluminescent properties of materials multilayered OLEDs were fabricated by employing DCCTBPA as a dopant material. This device showed the luminous and power efficiencies of 0.73 cd/A and 0.31 lm/W at 20 mA/cm(2), respectively, with the CIE coordinates of (0.66, 0.34) at 7.0 V. Compared to a device using DCCPA, this device using DCCTBPA showed the improved EL performances due to reducing the molecular aggregation and thus preventing concentration quenching.

  DOI：

  10.1080/15421406.2012.706556
• 作为产物：
  描述：

  2-(4-溴苯基)-1,3-二氧戊环 、 1-溴-4-(三甲基硅基)苯 、 3,5-二叔丁基苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 2-(二叔丁基膦)联苯 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 29.0h， 以29%的产率得到4-((3,5-di-tert-butylphenyl)-(4-(trimethylsilyl)phenyl)amino)benzaldehyde
  参考文献：
  名称：

  Synthesis and Electroluminescent Properties of Red Fluorescent 2-(6,8-di-tert-butyl-2-(4-((3,5-di-tert-butylphenyl)(4-(trimethylsilyl)phenyl)amino)styryl)-4H-chromen-4-ylidene)malononitrile (DCCTBPA) for Organic Light-Emitting Diodes (OLEDs)

  摘要：

  We synthesize a red fluorescent material, 2-(6,8-di-tert-butyl-2-(4-((3,5-di-tert-butylphenyl)(4-(trimethylsilyl)phenyl)amino)styryl)-4H-chromen-4-ylidene)malononitrile (DCCTBPA) using Knoevenagel condensation. To explore the electroluminescent properties of materials multilayered OLEDs were fabricated by employing DCCTBPA as a dopant material. This device showed the luminous and power efficiencies of 0.73 cd/A and 0.31 lm/W at 20 mA/cm(2), respectively, with the CIE coordinates of (0.66, 0.34) at 7.0 V. Compared to a device using DCCPA, this device using DCCTBPA showed the improved EL performances due to reducing the molecular aggregation and thus preventing concentration quenching.

  DOI：

  10.1080/15421406.2012.706556