1,4-Bis[[4-(bromomethyl)phenoxy]methyl]benzene | 683248-51-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-Bis[[4-(bromomethyl)phenoxy]methyl]benzene
• CAS: 683248-51-3
• 化学式: C₂₂H₂₀Br₂O₂
• 分子量: 476.208
• InChiKey: JOJRJVAOZVCQSV-UHFFFAOYSA-N

物化性质

• 沸点：
  557.9±45.0 °C(Predicted)
• 密度：
  1.498±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-Bis[[4-(bromomethyl)phenoxy]methyl]benzene 在 四氯化钛 、 potassium carbonate 、 锌 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 88.0h， 生成 (26Z)-2,8,15,21-tetraoxahexacyclo[26.2.2.24,7.210,13.216,19.222,25]tetraconta-1(31),4,6,10,12,16(36),17,19(35),22(34),23,25(33),26,28(32),29,37,39-hexadecaene
  参考文献：
  名称：

  Dioxastilbenophanes—synthesis and charge transfer complexation studies

  摘要：

  Intramolecular McMurry coupling of dialdehydes derived from xylenyl dibromide and 4-hydroxy benzaldehyde afforded cis-stilbenophanes along with cyclophane diols. Stilbenophanes with a large cavity were also synthesized. Charge transfer complexations of the stilbenophanes with TCNE, TCNQ and PQT were studied. Some stilbenophanes form a relatively stronger complex with PQT rather than with TCNE and TCNQ. (C) 2004 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2004.01.008
• 作为产物：
  描述：

  1,4-benzyloxy-bis(4-benzaldehyde) 在 sodium tetrahydroborate 、 三溴化磷 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 18.0h， 生成 1,4-Bis[[4-(bromomethyl)phenoxy]methyl]benzene
  参考文献：
  名称：

  Dioxastilbenophanes—synthesis and charge transfer complexation studies

  摘要：

  Intramolecular McMurry coupling of dialdehydes derived from xylenyl dibromide and 4-hydroxy benzaldehyde afforded cis-stilbenophanes along with cyclophane diols. Stilbenophanes with a large cavity were also synthesized. Charge transfer complexations of the stilbenophanes with TCNE, TCNQ and PQT were studied. Some stilbenophanes form a relatively stronger complex with PQT rather than with TCNE and TCNQ. (C) 2004 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2004.01.008