| 1384450-43-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1384450-43-4
• 化学式: C₁₇H₂₄N₂O₇
• 分子量: 368.387
• InChiKey: YBEFWZWCJFXKKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.77
• 重原子数：
  26.0
• 可旋转键数：
  13.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  132.81
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  、 4,34-Bis(2-anthracen-9-ylethynyl)-9,14,19,24,26,28,30,32-octamethoxyhexacyclo[21.2.2.23,6.28,11.213,16.218,21]pentatriaconta-1(25),3(35),4,6(34),8(33),9,11(32),13(31),14,16(30),18,20,23,26,28-pentadecaene 、 叔丁基二苯基氯硅烷 在 咪唑 、 4-二甲氨基吡啶 作用下， 以 氯仿 为溶剂， 反应 4.0h， 以71.2%的产率得到
  参考文献：
  名称：

  Rationally Designed Self-Immolative Rotaxane Sensor Based on Pillar[5]arene for Fluoride Sensing

  摘要：

  We develop a self-immolative rotaxane sensor for fluoride sensing based on host-guest interactions between pillar[5]arene and fluoride-promoted cleavage of Si-O bond. Because of the selective and fast reaction between silane and fluoride, the rotaxane sensor shows anion selectivity and rapid response. The self-immolative nature of the rotaxane improve its sensitivity. Moreover, a fluoride sensing test paper based on the rotaxane sensor is made, which shows the practicable application of the rotaxane sensor.

  DOI：

  10.1021/acs.orglett.0c02492
• 作为产物：
  描述：

  1,10-癸二醇 、 3,5-二硝基苯甲酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以81.8%的产率得到
  参考文献：
  名称：

  Rationally Designed Self-Immolative Rotaxane Sensor Based on Pillar[5]arene for Fluoride Sensing

  摘要：

  We develop a self-immolative rotaxane sensor for fluoride sensing based on host-guest interactions between pillar[5]arene and fluoride-promoted cleavage of Si-O bond. Because of the selective and fast reaction between silane and fluoride, the rotaxane sensor shows anion selectivity and rapid response. The self-immolative nature of the rotaxane improve its sensitivity. Moreover, a fluoride sensing test paper based on the rotaxane sensor is made, which shows the practicable application of the rotaxane sensor.

  DOI：

  10.1021/acs.orglett.0c02492

文献信息

• Preparation of two new [2]rotaxanes based on the pillar[5]arene/alkane recognition motif
  作者：Shengyi Dong、Chengyou Han、Bo Zheng、Mingming Zhang、Feihe Huang

  DOI：10.1016/j.tetlet.2012.05.028

  日期：2012.7

  Based on the pillar[5]arene/alkane recognition motif, two [2]rotaxanes were successfully prepared. Their formation was confirmed by NMR spectroscopy and ESI mass spectrometry. We also demonstrated that 3,5-dinitrophenyl group and 3,5-bis(trifluoromethyl)phenyl group are big enough to work as stoppers for DPPillar[5]arene, which lays a foundation for the preparation of more complex and functional supramolecular structures. (C) 2012 Published by Elsevier Ltd.