| 627509-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• CAS: 627509-75-5
• 化学式: C₂H₆OS*C₆H₅*C₁₄H₁₅N₂*Pt
• 分子量: 561.607
• InChiKey: GZYQBMLFLXGYNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.72
• 重原子数：
  27.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  42.85
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  bis(dimethylsulfoxide)diphenylplatinum(II) 、 6-(tert-butyl)-2,2'-bipyridine 以 丙酮 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Activation of a C−H Bond in a Pyridine Ring. Reaction of 6-Substituted 2,2‘-Bipyridines with Methyl and Phenyl Platinum(II) Derivatives:  N‘,C(3)-“Rollover” Cyclometalation

  摘要：

  The reaction of the electron-rich derivatives cis-[Pt(R)(2)(DMSO)(2)] (R = Me, Ph) with a series of 6-substituted-2,2'-bipyridines, HL, occurs with loss of methane or benzene, respectively, to yield cyclometalated platinum(II) species [Pt(R)(L)(DMSO)] where L is an anionic ligand N',C(3) coordinated. The unusual C-H activation entails a consecutive reaction process through a detectable intermediate. The reaction is peculiar of 6-substituted ligands: for comparison no reaction occurs with 6,6'-Me2-2,2'-bipy and an adduct, [Pt(R)(2)(HL)], is obtained with 5-Me-2,2'-bipy.

  DOI：

  10.1021/om0301583