[(1,3-bis(diisopropylphosphino)propane)Ni]2(μ-H)2 | 130777-68-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [(1,3-bis(diisopropylphosphino)propane)Ni]2(μ-H)2
• CAS: 130777-68-3
• 化学式: C₃₀H₇₀Ni₂P₄
• 分子量: 672.161
• InChiKey: SSIWTBCQCLNVIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.41
• 重原子数：
  36.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  [(1,3-bis(diisopropylphosphino)propane)Ni]2(μ-H)2 、 lithium triethylborohydride 以 甲苯 为溶剂， 以60%的产率得到[(1,3-bis(diisopropylphosphino)propane)Ni]2(μ-H)2 * LiBEt4
  参考文献：
  名称：

  Synthesis and structure of nickel(I) and platinum(I) hydride dimers having identical ancillary ligands

  摘要：

  The preparation and structures of two new dinuclear hydrides are reported. Reaction of KBEt3H with the nickel(II) precursor Ni(dippp)Cl-2 (dippp = 1,3 bis (diisopropylphosphino) propane) leads to the formation of the dinuclear complex [(dippp)Ni](2)(mu-H)(2). The single crystal X-ray structure of this Ni(I) dimer shows that the hydrides are symmetrically bridging with the two Ni(dippp) planes staggered with respect to each other by an angle of 75 degrees. The corresponding reaction of KBEt3H with the platinum(II) precursor Pt(dippp)I, leads to the formation of the dinuclear complex [(dippp)PtH](2). The single crystal X-ray structure of this Pt(I) dimer shows that the hydrides are terminal with the corresponding Pt(dippp) planes orthogonal (92.3 degrees) to each other. The structures of these two Group 10 hydride dimers are compared to the known Pd(I) dimer [(dippp)Pd](2)(mu-H)(2). Crystal data: [(dippp)Ni](2)(mu-H)(2) (1) (C30H70Ni2P4), monoclinic, a = 11.513(2), b = 16.420(3), c = 19.696(4) Angstrom, beta = 92.40(2)degrees, Z = 4, space group C2/c', [(dippp)PtH](2) (5) (C30H70P4Pt2), triclinic, a = 11.529(1), b = 16.581(1), c = 11.018(2) Angstrom, alpha = 91.11(1), beta = 107.10(1), gamma = 106.166(8)degrees, Z = 2, space group P1. The structures were solved by Patterson and direct methods and were refined by full-matrix least-squares procedures to R = 0.0503 and 0.042 (R-w = 0.0565 and 0.038) for 2487 and 6189 reflections, respectively. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05642-9
• 作为产物：
  描述：

  1,3-二(二异丙基膦酰)丙烷 以 乙醇 、 甲苯 为溶剂， 生成 [(1,3-bis(diisopropylphosphino)propane)Ni]2(μ-H)2
  参考文献：
  名称：

  Synthesis and structure of nickel(I) and platinum(I) hydride dimers having identical ancillary ligands

  摘要：

  The preparation and structures of two new dinuclear hydrides are reported. Reaction of KBEt3H with the nickel(II) precursor Ni(dippp)Cl-2 (dippp = 1,3 bis (diisopropylphosphino) propane) leads to the formation of the dinuclear complex [(dippp)Ni](2)(mu-H)(2). The single crystal X-ray structure of this Ni(I) dimer shows that the hydrides are symmetrically bridging with the two Ni(dippp) planes staggered with respect to each other by an angle of 75 degrees. The corresponding reaction of KBEt3H with the platinum(II) precursor Pt(dippp)I, leads to the formation of the dinuclear complex [(dippp)PtH](2). The single crystal X-ray structure of this Pt(I) dimer shows that the hydrides are terminal with the corresponding Pt(dippp) planes orthogonal (92.3 degrees) to each other. The structures of these two Group 10 hydride dimers are compared to the known Pd(I) dimer [(dippp)Pd](2)(mu-H)(2). Crystal data: [(dippp)Ni](2)(mu-H)(2) (1) (C30H70Ni2P4), monoclinic, a = 11.513(2), b = 16.420(3), c = 19.696(4) Angstrom, beta = 92.40(2)degrees, Z = 4, space group C2/c', [(dippp)PtH](2) (5) (C30H70P4Pt2), triclinic, a = 11.529(1), b = 16.581(1), c = 11.018(2) Angstrom, alpha = 91.11(1), beta = 107.10(1), gamma = 106.166(8)degrees, Z = 2, space group P1. The structures were solved by Patterson and direct methods and were refined by full-matrix least-squares procedures to R = 0.0503 and 0.042 (R-w = 0.0565 and 0.038) for 2487 and 6189 reflections, respectively. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05642-9