(E)-(2,4-di(biphenyl-4-yl)but-3-enyl)(phenyl)selane | 1415262-75-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: (E)-(2,4-di(biphenyl-4-yl)but-3-enyl)(phenyl)selane
• 英文别名: 1-phenyl-4-[(E)-3-(4-phenylphenyl)-4-phenylselanylbut-1-enyl]benzene
• CAS: 1415262-75-7
• 化学式: C₃₄H₂₈Se
• 分子量: 515.556
• InChiKey: JMDLUFCHEHWTJM-DYTRJAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.27
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-乙烯基联苯 、 二苯基二硒醚 在 碘 作用下， 以 1,2-二氯乙烷 为溶剂， 以31%的产率得到(E)-(2,4-di(biphenyl-4-yl)but-3-enyl)(phenyl)selane
  参考文献：
  名称：

  Selenenylations of alkenes with styrene nucleophiles

  摘要：

  Iodine-mediated addition reactions to alkenes with diphenyl diselenide using the same alkenes as nucleophiles are presented. The transformation proceeds under mild reaction conditions and the addition products were isolated in moderate to good yields. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.08.034

文献信息

• Selenenylations of alkenes with styrene nucleophiles
  作者：Elena Gabriele、Fateh V. Singh、Diana M. Freudendahl、Thomas Wirth

  DOI：10.1016/j.tet.2012.08.034

  日期：2012.12

  Iodine-mediated addition reactions to alkenes with diphenyl diselenide using the same alkenes as nucleophiles are presented. The transformation proceeds under mild reaction conditions and the addition products were isolated in moderate to good yields. (C) 2012 Elsevier Ltd. All rights reserved.